
“To protect the health of our state’s children,” California Governor Arnold Schwarzenegger signed legislation on October 14, 2007 prohibiting the use of phthalates (pronounced “thall-eights”) in childcare products designed for babies and children under three years of age.
Phthalates are used as plasticizers to soften polyvinyl chloride plastic, also known as PVC or vinyl, including a wide range of building products such as vinyl flooring, wallcovering and upholstery.
Phthalate plasticizers are not chemically bound to PVC. They have been found to leach, migrate or evaporate into indoor air and atmosphere, foodstuff, IV solutions and other materials, etc. Consumer products containing phthalates can result in human exposure through direct contact and use, indirectly through leaching into other products, or general environmental contamination. Humans are exposed through ingestion, inhalation, and dermal exposure during their whole lifetime, starting in the womb. Phthalates come in many different formulas. Most haven’t been tested or examined at all for human health impacts. The Consumer Product Safety Commission has noted that one phthalate formula common to certain building materials — DINP [1] — is a mixture of up to 100 chemical variants, of which only five have been minimally studied [2]. Others have been found to pose a risk of serious negative health impacts at very low doses.
Phthalates have been shown to have negative effects on human health including interference with the natural functioning of the hormone system, and reproductive and genital defects. Phthalates may lower sperm count and are associated with the risk factors for testicular cancer, as well as early onset of puberty and premature birth.
In June 2005, HBN discussed recent research findings that the cumulative impact of different phthalates leads to an exponential increase in associated harm, and documented levels of phthalates found in humans at levels higher than levels shown to cause adverse health effects. A 2007 study concluded that the exposure of children to phthalates exceeds that in adults, warning, “Current human biomonitoring data prove that the tolerable intake of children is exceeded to a considerable degree, in some instances up to 20-fold” [3].
Phthalates have been found in high quantities in studies of household dust. Other studies have documented links between childhood asthma and phthalate exposure from vinyl flooring. Because phthalates are not a volatile organic compound (VOC), however, they are usually not accounted for by indoor air quality standards such as those used to certify green building materials.
California now joins the EU [4] in restricting the use of phthalates in the use of children’s products, and many other US states are expected to take up legislation similar to that signed by Governor Schwarzenegger [5].
Like the human carcinogens vinyl chloride and dioxin, phthalates are uniquely associated with PVC [6]. It is this triple threat from PVC that distinguishes it as the worst plastic for environmental health and green building. Regrettably, there are still few restrictions on the use of vinyl in green buildings.
Toxic chemicals common to home furnishings and electronic equipment have been found in household dust, including chemicals internationally recognized as harmful or toxic to the immune and reproductive systems; babies and young children are particularly at risk from exposure. That is the finding of a 2005 report, Sick of Dust: Chemicals in Common Products, which investigated six classes of chemicals in dust samples taken from 70 homes in seven states across the U.S. Among the chemicals documented in household dust are two — phthalate plasticizers and organotin stabilizers — that are ubiquitous in PVC vinyl building materials.
of phthalates manufactured are used in PVC products, and have been documented as leaching from shower curtains and flooring.
Animal studies have found phthalates disrupt reproductive systems, particularly in male offspring, and can contribute to male infertility. Phthalates have also been linked to asthma and respiratory problems in children.
Organotins, which are found in PVC water pipes, PVC food packaging materials, and many other consumer products, are poisonous in even small amounts, and can disrupt the hormone, reproductive, and immune systems.
In addition to the two chemicals commonly associated with PVC building materials, the report also found high concentrations of brominated flame retardants, which are incorporated into many plastics, including PVC, and electrical goods. Studies have revealed the breast milk of American women has 10 to 100 times higher concentration of PBDE, a type of flame retardant, than European women. According to Sick of Dust, a recent study indicates that levels of PBDE in Swedish breast milk began to decrease in 1997, possibly due to a voluntary phase-out of penta-DBE.
These findings add to the momentum of an anti-PVC movement which, according to a feature article in the Christian Science Monitor, is “picking up steam,” and provide additional ammunition for the many commenters who took aim at the USGBC’s draft PVC report that found “PVC does not emerge as a clear winner or loser.”
The Sick of Dust report ranks brand name companies and retailers on their use of hazardous chemicals, and provides an outline of fundamental changes needed to bring American chemical regulation up to a level that will protect basic health today and in future generations. But the easiest way to eliminate phthalates and organotins from household dust is to eliminate PVC from the household.
In the last 40 years, polyvinyl chloride plastic (PVC) has become a major building material. Global vinyl production now totals over 30 million tons per year, the majority of which is directed to building applications, furnishings, and electronics.
The hazards posed by dioxins, phthalates, metals, vinyl chloride, and ethylene dichloride are largely unique to PVC, which is the only major building material and the only major plastic that contains chlorine or requires plasticizers or stabilizers. PVC building materials therefore represent a significant and unnecessary environmental health risk, and their phase-out in favor of safer alternatives should be a high priority. PVC is the antithesis of a green building material. Efforts to speed adoption of safer, viable substitute building materials can have significant, tangible benefits for human health and the environment. This report describes the full life cycle of PVC in the contemporary building industry from production to disposal.