Read Habitable’s new report “Designing Out Plastics: A Blueprint for Healthier Building Materials”
Read Habitable’s new report “Designing Out Plastics: A Blueprint for Healthier Building Materials”
Read Habitable’s new report “Designing Out Plastics: A Blueprint for Healthier Building Materials”
Read Habitable’s new report “Designing Out Plastics: A Blueprint for Healthier Building Materials”
Read Habitable’s new report “Designing Out Plastics: A Blueprint for Healthier Building Materials”
Read Habitable’s new report “Designing Out Plastics: A Blueprint for Healthier Building Materials”

“To protect the health of our state’s children,” California Governor Arnold Schwarzenegger signed legislation on October 14, 2007 prohibiting the use of phthalates (pronounced “thall-eights”) in childcare products designed for babies and children under three years of age.

Phthalates are used as plasticizers to soften polyvinyl chloride plastic, also known as PVC or vinyl, including a wide range of building products such as vinyl flooring, wallcovering and upholstery.

Phthalate plasticizers are not chemically bound to PVC. They have been found to leach, migrate or evaporate into indoor air and atmosphere, foodstuff, IV solutions and other materials, etc. Consumer products containing phthalates can result in human exposure through direct contact and use, indirectly through leaching into other products, or general environmental contamination. Humans are exposed through ingestion, inhalation, and dermal exposure during their whole lifetime, starting in the womb. Phthalates come in many different formulas. Most haven’t been tested or examined at all for human health impacts. The Consumer Product Safety Commission has noted that one phthalate formula common to certain building materials — DINP [1] — is a mixture of up to 100 chemical variants, of which only five have been minimally studied [2]. Others have been found to pose a risk of serious negative health impacts at very low doses.

Phthalates have been shown to have negative effects on human health including interference with the natural functioning of the hormone system, and reproductive and genital defects. Phthalates may lower sperm count and are associated with the risk factors for testicular cancer, as well as early onset of puberty and premature birth.

In June 2005, HBN discussed recent research findings that the cumulative impact of different phthalates leads to an exponential increase in associated harm, and documented levels of phthalates found in humans at levels higher than levels shown to cause adverse health effects. A 2007 study concluded that the exposure of children to phthalates exceeds that in adults, warning, “Current human biomonitoring data prove that the tolerable intake of children is exceeded to a considerable degree, in some instances up to 20-fold” [3].

Phthalates have been found in high quantities in studies of household dust. Other studies have documented links between childhood asthma and phthalate exposure from vinyl flooring. Because phthalates are not a volatile organic compound (VOC), however, they are usually not accounted for by indoor air quality standards such as those used to certify green building materials.

California now joins the EU [4] in restricting the use of phthalates in the use of children’s products, and many other US states are expected to take up legislation similar to that signed by Governor Schwarzenegger [5].

Like the human carcinogens vinyl chloride and dioxin, phthalates are uniquely associated with PVC [6]. It is this triple threat from PVC that distinguishes it as the worst plastic for environmental health and green building. Regrettably, there are still few restrictions on the use of vinyl in green buildings.

SOURCES

  1. Diisononyl phthalate, a general use vinyl plasticizer. It is the primary plasticizer used in vinyl toys, though it finds many other applications such as garden hoses, shower curtains, vinyl flooring and wall covering. Source: http://www.phthalates.org/glossary.asp [link no longer available]
  2. “Aggregate Exposures to Phthalates in Humans,” Health Care Without Harm, July 2002. http://www.noharm.org/lib/downloads/pvc/Agg_Exposures_to_Phthalates.pdf, p.16, footnote 149 Heudorf et al., 2007. “Phthalates: Toxicology and exposure“. International Journal of Hygiene and Environmental Health. Article in Press.
  3. Heudorf et al., 2007. “Phthalates: Toxicology and exposure“. International Journal of Hygiene and Environmental Health. Article in Press.
  4. “Permanent EU ban on phthalates in toys and childcare articles is published” TDCTrade.com website, Feb 03, 2006, http://www.hktdc.com/info/mi/a/baeu/en/1X008GDB/1/Business-Alert-%E2%80%93-EU/Permanent-EU-ban-on-phthalates-in-toys-and-childcare-articles-is-published.htm
  5. “A nationwide toxic toy ban likely to follow state lead” SF Chronicle, October 16, 2007, http://www.sfgate.com/cgi-bin/article.cgi?file=/c/a/2007/10/16/MNT0SQDJV.DTL
  6. About 80 to 90% of phthalate production goes into PVC (Costner, Pat et al. 2005, “Sick of Dust: Chemicals in Common Products–A Needless Health Risk in Our Homes”, Safer Products Project, http://safer-products.org/downloads/Dust Report.pdf and the Phthalates Information Centre Europe http://www.phthalates.com

A week after the US Green Building Council’s (USGBC) Technical Science Advisory Committee determined that PVC was one of the most unhealthy building materials in part due to occupational exposures to vinyl chloride, the federal Chemical Safety Board (CSB) found that a massive release of vinyl chloride led to the explosion that killed 5 workers at a PVC factory in Illiopolis, Illinois on April 23, 2004.

The CSB Investigation Report is made all the more relevant to green building professionals in light of the USGBC’s finding that PVC flooring ranked absolute worst in both human health and environmental factors compared to the alternatives reviewed. The destroyed factory, owned by Formosa Plastics, had been a major supplier of vinyl resin for Armstrong floors.

The CSB is the industrial equivalent of the National Transportation Safety Board (NTSB), the agency that rushes investigators to the scene of plane crashes, train derailments and the like. [1] The CSB’s March 6, 2007 report found among other things that the cause of this accident, “inadvertently draining a reactor, is a serious hazard in the PVC manufacturing process.” [2] Indeed just 60 days before the fatal explosion, workers at the same facility accidentally released an undisclosed amount of vinyl chloride. The report also notes that 8,000 pounds of vinyl chloride were released by accident in June 2003 at the company’s Baton Rouge, LA facility. [3] A year after the explosion, in May 2005, another 2,500 pounds of vinyl chloride were accidentally released from the company’s Delaware City, DE location. [4] Each release was caused by the same problems which led to the catastrophe at the Illiopolis facility in April 2004. Other PVC factories owned by Formosa have also suffered catastrophic explosions in the recent past. [5]

The chemical at issue, vinyl chloride, is a human carcinogen whose total danger is believed by many to be underestimated by the EPA. A 2005 study in the peer reviewed journal American Health Perspectives found that the EPA employed discredited scientific practices at the behest of the chemical industry in order to lower estimates of vinyl chloride’s cancer potency by tenfold. [6]

The USGBC’s study of PVC found it “consistently among the worst materials for human health impacts” based upon exceedingly conservative estimates of impact. To understand how conservative, consider that its evaluation of PVC only accounted for exposures from normal operations to workers in the factory and neighbors at the fenceline. The health impacts of the extraordinary accidental releases from Formosa’s facilities described above — and the deadly explosions that can follow as at Illiopolis — are beyond the reach of tools like LCA and risk analysis.

This CSB report further underscores the significance of the USGBC’s decision to be guided by the Precautionary Principle in its evaluation of green building materials and to fully consider the impacts of manufacturing processes on production workers. It is the essence of precaution to avoid hazards and risks that are avoidable. So remember this the next time you specify pipe, roofing membranes, wall coverings and especially flooring: the chemical that killed those 5 men in Illiopolis is essential and unique to only one material you are considering: PVC plastic, also known as vinyl. [7]

SOURCES

  1. The CSB is an independent federal agency charged with investigating industrial chemical accidents. The agency’s board members are appointed by the president and confirmed by the Senate. CSB investigations look into all aspects of chemical accidents, including physical causes such as equipment failure as well as inadequacies in regulations, industry standards, and safety management systems. The Board does not issue citations or fines but does make safety recommendations to plants, industry organizations, labor groups, and regulatory agencies such as OSHA and EPA.
  2. US Chemical Safety and Hazard Investigation Board Investigation Report, Formosa Plastics Corp., Illiopolis, Illinois, April 23, 2004 p. 29. http://www.csb.gov/completed_investigations/docs/FormosaPlasticsIlliopolisReport.pdf
  3. Ibid. p. 28
  4. Ibid. p. 29
  5. http://abclocal.go.com/wpvi/story?section=nation_world&id=3514274 [link no longer available]
  6. Jennifer Beth Sass, Barry Castleman and David Wallinga. “Vinyl Chloride: A Case Study of Data Suppression and Misrepresentation,” Environmental Health Perspectives, published online 24 March 2005, doi:10.1289/ehp.7716, http://www.ehponline.org/members/2005/7716/7716.html
  7. To be sure, vinyl chloride is not the only avoidable risk in the production of flooring, or plastics, or materials generally. However, the risk of explosion is only one of the negative environmental health consequences of vinyl chloride whose use is both essential and unique to PVC plastic. Related impacts include dioxin emissions from manufacture and fire, the use and release of toxic additives such as cadmium and lead stabilizers and phthalate softeners, and the threats associated with the production of massive quantities of chlorine gas as the basic building block of vinyl chloride production. These factors lead HBN to the conclusion that PVC is the worst plastic for the environment.

Lessons From The Formosa PVC Plant, Illiopolis, Illinois

One morning ten years ago, I was at work on a book about environmental health when the phone rang. It was my Uncle Roy. He wanted me to know that a developer had come to town peddling a plan to construct a giant waste incinerator in the cornfield next to his own. What the man was planning to burn in it, he said, was old auto interiors, including a lot of PVC plastic. If the people of the township went along, the company would build the school a new library.

Now how did they know we needed a library, my uncle wondered. And what did I know about a chemical called dioxin? Funny he should ask. I was just drafting that chapter.

So I took leave of the Harvard Medical School Library and went back home to library-less central Illinois to throw my hat in the ring with my mother’s brother and a group of other farmers who had vowed to fight the incinerator.

And we won. Not only did Forrest, Illinois vote down the incinerator plan, it was defeated in six other small, impoverished farming communities where the same developer had dangled it. People looked out at their turkeys, hogs, and fields of corn and imagined what could happen if one semi-truck full of dioxin-laden incinerator ash overturned on a windy day. It just wasn’t worth the risk, they decided.

A decade later, central Illinoisians are confronted with a similar choice. This time it involves the manufacture of PVC rather than its destruction.

On April 23, 2004, the PVC plant in Illiopolis, Illinois exploded, spewing fireballs into the night sky, cutting power and water, and sending all of the village’s 900-something inhabitants into makeshift shelters in distant towns. Four workers were killed instantly. Three were hospitalized.

The U.S. Chemical Safety and Hazard Investigation Board conducted an investigation of the long-term environmental health effects of the explosion. Its chairwoman, Carolyn W. Merritt, called the explosion at Illiopolis among the most serious the agency has ever investigated. So far, no signs of air or water contamination have been uncovered. On the other hand, at this writing, investigators were not able to get closer than a quarter mile to the plant because of safety concerns.

But, let’s suppose that no chemical contamination from the plant’s destruction was found. Let’s imagine that thousands of pounds of vinyl chloride and vinyl acetate-which workers were mixing at the time of detonation-somehow all burned up without leaving behind any toxic residues in the community’s air or water or farm fields. It would still be a bad idea to rebuild this plant. Which is the current plan.

Each year, the Illiopolis PVC plant releases into the air more than 40,000 pounds of vinyl chloride, a recognized human carcinogen and reproductive toxicant. It releases another 40,000 pounds of vinyl acetate, a suspected carcinogen and neurotoxin. In other words, under normal operating conditions, this plant routinely discharges into the surrounding community more than 40 tons of toxic chemicals annually. That works out to 220 pounds of known and probable carcinogens every single day. The weight of a large man.

Such releases make this plant one of Illinois’ biggest polluters. But when you stack the Illiopolis facility next to all the other PVC plants in the United States, of which there are about 40, it pales in comparison. Its emissions are far from the worst. (Oxyvinyl in Pasadena, Texas releases more than 100,000 pounds of vinyl chloride annually.)

Even absent horrific accidents like the one in Illiopolis, which made headlines across the world, there seems to be no way of making PVC without contaminating somebody’s beloved hometown with cancer-causing substances. And that fact alone should be sufficient to compel us to seek out substitutes for PVC for all its various uses.

Here are the names of those who died in the Illiopolis explosion: Joseph Machalek, age 50; Larry Graves; age 47; Glenn Lyman, age 49; Linda Hancock, age 56.

What are the names of those who have died of cancer caused by the routine operation of this same plant over the years? Who have suffered miscarriages, birth defects, or neurological disorders due to their constant exposure to reproductive and neurological poisons? It is an unknown and unknowable number. But it may well exceed four. And it may be too high a price to pay for vinyl.

Sandra Steingraber, Ph.D., grew up in Pekin, Illinois. She is a biologist and author of the book Living Downstream: An Ecologist Looks at Cancer and the Environment. She is currently on the faculty of Ithaca College in New York.

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