Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.
Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.
Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.
Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.
Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.
Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.

…that some chemicals used for stain or water repellency in building products last longer than nuclear waste?

In fact, as far as can be determined, the most studied of these perfluorinated chemicals, perfluorooctane sulfonate (PFOS) – formerly the key chemical in Scotchgard™ – never breaks down in the environment.[1]

Perfluorinated compounds (PFCs) are manmade compounds, based on the element fluorine, and are the key ingredients in stain- and water-repellent treatments such as Teflon®, Crypton® and Crypton Green®, Gore™, and Stainmaster®, and in nanotech products such as Nano-Tex™ and GreenShield™.[2] Scientists have raised concerns about PFCs because they are persistent, bioaccumulative, and toxic. Moreover, biomonitoring studies confirm widespread human exposure to this class of compounds.

Scientific studies have linked PFCs with developmental toxicity, cancer, thyroid, liver and immune system functions, cholesterol increases, and low birth measurements in newborn humans.[3] The health issues associated with PFCs, coupled with alarming data about the increasing chemical burden of these compounds in our bodies,[4] as well as the widespread exposure in wildlife, have prompted scientists and public health experts to express increasing concern about continued use of these chemicals.

In May 2009, the Stockholm Convention on Persistent Organic Pollutants (POPs) added PFOS to a growing list of chemicals recognized by international treaty as chemicals of greatest concern to be reduced or eliminated in the global environment, putting them in league with widely recognized threats such as dioxin and PCBs.

In the U.S., most major fabric treatment brands continue to use PFCs as chemical manufacturers rush to replace the most well-studied PFCs with similar fluorinated compounds that have not been heavily scrutinized. Although chemical manufacturers such as DuPont resist releasing information about the new compounds, it is clear that some are virtually unstudied, and some that scientists have studied are breaking down to PFOS and perfluorooctanic acid (PFOA), which would add to the reservoir of these persistent contaminants in the general environment. In June 2008, the Environmental Working Group (EWG) released a report on PFCs, which uncovered evidence that manufacturers’ own tests showed that many of the alternative chemicals lead “to a conclusion of substantial risk to human health or to the environment.”[5]

Like nuclear waste, the problem of PFCs isn’t going away. Still, there are steps that can be taken today to stem the tide of PFCs accumulating in our bodies. For many of the PFC applications, we can start out by simply asking ourselves whether we really need these chemicals at all.

For those wanting to understand more about PFCs and potential health concerns, HBN and Kaiser Permanente have produced a paper that examines PFCs in more detail.

SOURCES

  1. Co-operation on Existing Chemicals – Hazard Assessment of Perfluorooctane Sulfonate and its Salts. Environment Directorate Joint Meeting of the Chemicals Committee and the Working Party on Chemicals, Pesticides, and Biotechnology, Organisation for Economic Co-operation and Development, Paris. November 2002. http://www.oecd.org/dataoecd/23/18/2382880.pdf.
  2. In addition to these products which are widely used to create water and soil repellency in fabric, furniture, and carpet, PFCs are found elsewhere including fire fighting foams, metal plating, and within the photographic industry.
  3. References for these health impacts and the chemical burden concerns outlined below can be found in the report Perfluorinated Compounds (PFCs) and Human Health Concerns, from the Global Health and Safety Initiative, http://www.healthybuilding.net/healthcare/2009-04-20PFCs_fact_sheet.pdf.
  4. Calafat A, Kuklenyik Z, Reidy J, Caudill S, Tylly J, Needham L. Serum Concentrations of 11 Polyfluoroalkyl Compounds in the U.S. Population: Data from the National Health and Nutrition Examination Survey (NHANES) 1999-2000. Centers for Disease Control and Prevention. 2007. http://www.cdc.gov/exposurereport/perfluorinated_compounds_3.html.
  5. Nadenko O, Sharp R. Credibility Gap: Toxic Chemicals in Food Packaging and DuPont’s Greenwashing: New Chemicals and Risks are Confidential. Environmental Working Group Report. June 2008. http://www.ewg.org/reports/teflongreenwash. Accessed April 15, 2009.

Lessons From The Formosa PVC Plant, Illiopolis, Illinois

One morning ten years ago, I was at work on a book about environmental health when the phone rang. It was my Uncle Roy. He wanted me to know that a developer had come to town peddling a plan to construct a giant waste incinerator in the cornfield next to his own. What the man was planning to burn in it, he said, was old auto interiors, including a lot of PVC plastic. If the people of the township went along, the company would build the school a new library.

Now how did they know we needed a library, my uncle wondered. And what did I know about a chemical called dioxin? Funny he should ask. I was just drafting that chapter.

So I took leave of the Harvard Medical School Library and went back home to library-less central Illinois to throw my hat in the ring with my mother’s brother and a group of other farmers who had vowed to fight the incinerator.

And we won. Not only did Forrest, Illinois vote down the incinerator plan, it was defeated in six other small, impoverished farming communities where the same developer had dangled it. People looked out at their turkeys, hogs, and fields of corn and imagined what could happen if one semi-truck full of dioxin-laden incinerator ash overturned on a windy day. It just wasn’t worth the risk, they decided.

A decade later, central Illinoisians are confronted with a similar choice. This time it involves the manufacture of PVC rather than its destruction.

On April 23, 2004, the PVC plant in Illiopolis, Illinois exploded, spewing fireballs into the night sky, cutting power and water, and sending all of the village’s 900-something inhabitants into makeshift shelters in distant towns. Four workers were killed instantly. Three were hospitalized.

The U.S. Chemical Safety and Hazard Investigation Board conducted an investigation of the long-term environmental health effects of the explosion. Its chairwoman, Carolyn W. Merritt, called the explosion at Illiopolis among the most serious the agency has ever investigated. So far, no signs of air or water contamination have been uncovered. On the other hand, at this writing, investigators were not able to get closer than a quarter mile to the plant because of safety concerns.

But, let’s suppose that no chemical contamination from the plant’s destruction was found. Let’s imagine that thousands of pounds of vinyl chloride and vinyl acetate-which workers were mixing at the time of detonation-somehow all burned up without leaving behind any toxic residues in the community’s air or water or farm fields. It would still be a bad idea to rebuild this plant. Which is the current plan.

Each year, the Illiopolis PVC plant releases into the air more than 40,000 pounds of vinyl chloride, a recognized human carcinogen and reproductive toxicant. It releases another 40,000 pounds of vinyl acetate, a suspected carcinogen and neurotoxin. In other words, under normal operating conditions, this plant routinely discharges into the surrounding community more than 40 tons of toxic chemicals annually. That works out to 220 pounds of known and probable carcinogens every single day. The weight of a large man.

Such releases make this plant one of Illinois’ biggest polluters. But when you stack the Illiopolis facility next to all the other PVC plants in the United States, of which there are about 40, it pales in comparison. Its emissions are far from the worst. (Oxyvinyl in Pasadena, Texas releases more than 100,000 pounds of vinyl chloride annually.)

Even absent horrific accidents like the one in Illiopolis, which made headlines across the world, there seems to be no way of making PVC without contaminating somebody’s beloved hometown with cancer-causing substances. And that fact alone should be sufficient to compel us to seek out substitutes for PVC for all its various uses.

Here are the names of those who died in the Illiopolis explosion: Joseph Machalek, age 50; Larry Graves; age 47; Glenn Lyman, age 49; Linda Hancock, age 56.

What are the names of those who have died of cancer caused by the routine operation of this same plant over the years? Who have suffered miscarriages, birth defects, or neurological disorders due to their constant exposure to reproductive and neurological poisons? It is an unknown and unknowable number. But it may well exceed four. And it may be too high a price to pay for vinyl.

Sandra Steingraber, Ph.D., grew up in Pekin, Illinois. She is a biologist and author of the book Living Downstream: An Ecologist Looks at Cancer and the Environment. She is currently on the faculty of Ithaca College in New York.

In the last 40 years, polyvinyl chloride plastic (PVC) has become a major building material. Global vinyl production now totals over 30 million tons per year, the majority of which is directed to building applications, furnishings, and electronics.

The hazards posed by dioxins, phthalates, metals, vinyl chloride, and ethylene dichloride are largely unique to PVC, which is the only major building material and the only major plastic that contains chlorine or requires plasticizers or stabilizers. PVC building materials therefore represent a significant and unnecessary environmental health risk, and their phase-out in favor of safer alternatives should be a high priority. PVC is the antithesis of a green building material. Efforts to speed adoption of safer, viable substitute building materials can have significant, tangible benefits for human health and the environment.  This report describes the full life cycle of PVC in the contemporary building industry from production to disposal.