This follows a recent report from the National Academies of Science (NAS), “A Class Approach to Hazard Assessment of Organohalogen Flame Retardants,” which recommended evaluating similar flame retardants together as “the only possible practical approach.” HBN has championed this class-based approach because the alternative, regulating chemicals one at a time, often leads to regrettable substitutions, in which the simplest replacement for a hazardous chemical is a structural relative with similar desirable properties and similar toxicity. 

In this report, NAS divided the broad class of organohalogen flame retardants into 14 subclasses based on a combination of chemical structure and predicted biological activity. The subclasses contain between 4 to 22 chemicals, though the NAS report emphasizes that this inventory is not necessarily comprehensive. HBN has incorporated these 14 subclasses (listed below) as compound groups, to make it easier for the community to review and discuss them. If you’re not a member of Pharos yet, you can register for free and see the hazards of the chemicals in two of the subclasses (alicycles or benzene aliphatics). Not surprisingly, within a subclass, many chemicals share the same hazards!

Compound groups are groups of chemicals that share structural or chemical features. In most cases, chemical regulations restrict the use of individual substances, though in some cases, they restrict a group or class of chemicals, such as organohalogen flame retardants or lead compounds. In cases like these, HBN creates a compound group for each class (and subclass) of chemicals. While a class-based regulatory approach can be more comprehensive, it can also be difficult to implement, since regulatory agencies rarely specify the chemicals within a group. To facilitate implementation of these restrictions, Pharos staff assigns specific chemicals to compound groups, making sure warnings from hazard lists are associated with them. This allows manufacturers to be confident that when they screen their product ingredients in Pharos, they will be alerted to any relevant regulations or hazards. This can also make it easier for companies using these chemicals to assign the appropriate hazards to improve communication about workplace safety.

These 14 new compound groups join over 600 other compound groups populated by Healthy Building Network’s research team and are available in our Pharos tool. Use these tools today to look up hazard data on over 140,000 chemicals for 22 hazard endpoints from >80 authoritative data sources. You can also search for chemicals by function, and use comparison tools to find safer alternatives.

As with all work in Pharos, compound groups are open and collaborative. We welcome suggestions for additions and invite all members of the community to initiate and engage in discussions about these and other chemical hazard issues.

14 Subclasses of Halogenated Flame Retardants

• Polyhalogenated alicycles
• Polyhalogenated aliphatic carboxylate
• Polyhalogenated aliphatic chains
• Polyhalogenated benzene alicycles
• Polyhalogenated benzene aliphatics and functionalized
• Polyhalogenated benzenes
• Polyhalogenated bisphenol aliphatics and functionalized
• Polyhalogenated carbocycles
• Polyhalogenated diphenyl ethers
• Polyhalogenated organophosphates
• Polyhalogenated phenol derivatives
• Polyhalogenated phenol-aliphatic ethers
• Polyhalogenated phthalates/benzoates/imides
• Polyhalogenated triazines

Every day we come in contact with a large number of chemical products. Think of the last time you walked through a space being remodeled, or sat in a new car and thought “what’s that smell?” Your body notices that smell because a chemical or substance is interacting with the smell receptors in your nose. The same characteristics that allow it to interact with your nose could make those chemicals affect the body in other ways too—sometimes causing harm. The more invisible moments occur when sleeping on your mattress filled with flame retardants or using your personal care products while getting ready for work. Perhaps you work in a factory, as a contractor installing products, or some other job requiring direct contact with a variety of chemicals. The list (both visible and invisible) goes on and on. While a one-time exposure might not lead to health effects, a life-time of exposure and buildup to these chemicals can. More and more scientific evidence links these chemical exposures to diseases like cancer and diabetes, as well as developmental delays, reproductive health issues, and Autism Spectrum Disorder1. 

There are three main exposure pathways: 1) inhalation – breathing in contaminated air, 2) ingestion – the inadvertent passing of dust or other chemical residues from hands to mouth, and 3) because our skin is like a sponge – absorption through dermal contact. According to the Environmental Working Group (EWG), babies still in the womb are exposed to more than 200 chemicals that pass from their mother through the umbilical cord2. This should make you wonder—what are the chemicals I may not realize are entering my body? There is a term used to describe the load of chemicals in the human body—body burden.

You can also download their Detox Me Now App for more tips.

Biomonitoring studies similar to Silent Spring’s are springing up in recent years, as have articles about their results, such as this story in the Guardian. For only a few hundred dollars, consumers can know the exact chemical composition of their bodies. For those who find sample submission undesirable, HBN has added a new feature in our Pharos platform that provides links to biomonitoring databases with information on chemicals identified in the bodies of individuals from different regional communities. The results continually shed light on the need for greater industrial transparency and a transition to safer products. 

This is one more example of why HBN passionately paves the way to safer products, offering recommended alternatives from expert chemical analysis and by fostering collaborative industry partnerships.

At this point, there is an urgency because people are now experiencing the effects of a warming planet:storms, fires, rising tides, health impacts from warmer temperatures, and more.

To date, climate plans have focused on strategies related to renewable and clean energy, greater efficiency, emissions reduction, etc., especially as it relates to building operations and transportation. However, that is only one side of the (enormous) coin, and it misses key opportunities on the opposite side. It is akin to making the decision to improve your health by incorporating an exercise plan, but continuing a diet of nutritionally deficient and unhealthy foods. You will only get so far, and your dedication to exercise will be undercut by your fast food burgers and supersized fries. 

The other side of the coin? If building and transportation energy and emissions reduction is “heads,” what could be so immense that it fills the flipside? The “tails” of that coin is the vast quantities of products being produced, its emissions and pollution, and the need for toxic chemical mitigation. The missing piece in effective climate mitigation and improved global health is a toxic-free, recyclable product cycle (low-waste and closed-loop).

As energy efficiency and renewable energy gains reduce the carbon footprint of the transportation and building operations sectors, addressing product production assumes an even greater importance. Successfully addressing climate change requires a revolutionary change in how we design and manufacture materials, towards a circular, closed-loop economy. But materials cannot flow effectively in a closed-loop if they are contaminated with toxic chemicals. Safe first, and then circular is possible. 

The urgency to mitigate toxics must be on par with the urgency for clean and renewable energy – they are two sides of the same coin. Failing to recognize this, and create holistic, compatible solutions, will undermine our goals to manage climate change and improve global health. 

To create a truly sustainable circular economy, we must know what’s in the materials and products we choose, and those choices should focus on optimized chemistry for human and environmental health. Only then will we have the building blocks for a circular economy.

A circular economy is fueled by the creation and retention of value. By keeping material streams as pure as possible from the beginning and through the entire use cycle, the full value of a material is retained. Value retention is key to activating the systems that make the circular economy function, including the incentive for manufacturers to take back products because they have value and the motivation for entrepreneurs to create robust secondary markets.

Not all materials are fit for a circular economy, however. When they contain chemicals that are hazardous for humans or the environment, they provide little to no value in supporting  circularity. Fortunately there are ways to choose materials that are safe AND circular so you can build a better offering for your users and introduce valuable inputs for a sustainable economy.

To help designers, entrepreneurs, and innovators make positive materials choices and integrate better chemistry into the design process from the very start, the Ellen MacArthur Foundation and the Cradle to Cradle Products Innovation Institute (C2C PII) have released a new series of advanced learning modules as part of the foundation’s Circular Design Guide, which was co-created with IDEO.

You’ll find them in the Methods section of the guide (scroll to the “Advanced” section), which aims to fuel design thinking for the circular economy by challenging traditional design methods, delivering new approaches, and introducing users to circular economy concepts as well as techniques updated for this new economic framework.