READ HABITABLE’S NEW REPORTDesigning Out Plastics: A Blueprint for Healthier Building Materials
HealthHealthy Environments: What’s New (and What’s Not) With PVC
Report
This paper was prepared by Perkins+Will, in partnership with Healthy Building Network (HBN), as part of a larger effort to promote health in the built environment. Indoor environments commonly have higher levels of pollutants, and architects and designers may frequently have the opportunity to help reduce or mitigate exposures.
The purpose of this report is to present information on the environmental and health hazards of PVC, with an emphasis on information found in government sources. This report is not intended to be a comprehensive analysis of all aspects of the PVC lifecycle, or a comprehensive comparative analysis of polymer lifecycles. Rather, in light of recent claims that PVC formulas have been improved by reducing certain toxic additives, this paper reviews contemporary research and data to determine if hazards are still associated with the lifecycle of PVC. This research has been surveyed from a perspective consistent with the precautionary principle, which, as applied, means that where there is some evidence of environmental or human health impact of PVC that reasonable alternatives should be used where possible. Furthermore, and more generally, this paper is intended to build greater awareness of this common building material.
HealthPhthalate-free Plasticizers in PVC
Report
This Healthy Building Network (HBN) Research Brief examines replacements for phthalate plasticizers in Polyvinyl Chloride (PVC) building materials. Plasticizers are added to PVC to make it flexible, but since they are not tightly bound to the PVC molecules, they migrate from PVC products.
Phthalates, the most commonly used plasticizers in PVC, are known endocrine disruptors – chemicals that interfere with hormone signaling, which is especially critical to early childhood development. Additionally, many phthalates are known carcinogens and reproductive and developmental toxicants. Exposures to these toxic plasticizers from PVC products can occur throughout their lifecycle. Therefore, it is crucial that PVC products containing phthalate plasticizers be eliminated from the built environment.
HealthIgniting the Debate on Flame Retardants
People
Arlene Blum is a biophysical chemist, author and mountaineer.
She is the founder and executive director of the Green Science Policy Institute which works with scientists, government, industry, and non-profits to facilitate more informed decision-making about flame retardants and other chemicals used in consumer and building products.
Healthy Building Network founder Director Bill Walsh caught up with Elaine, recording the following conversation:
Bill Walsh:
How did you get started working on flame retardants?
Arlene Blum:
Thirty years ago, as a researcher at the University of California, Berkeley, I published a paper in Science magazine showing that “Tris” flame retardants in children’s sleepwear caused mutations, were possible cancer hazards, and migrated from pajamas into children. The flame retardants were removed from children’s sleepwear in 1977, but chlorinated tris is now back in use in foam in furniture and other products.
BW:
Why are you so concerned about flame retardants in building materials?
AB:
If a building contains halogenated flame retardants in the insulation, they can filter into the building throughout its life and also form toxic dioxins if the building burns.
I know it’s a real dilemma for people when they learn that plastic insulation materials, such as polystyrene, polyisocyanurate, and polyurethane, that can help reduce climate change, often contain flame retardants which can cause serious health and environmental harm. But the good news is that this is a problem that can be solved.
Once green building professionals understand the issue, they can move to safer substitutes and strategies that don’t have potential adverse health impacts. In fact of the various groups with which I’ve worked on reducing toxics in products, the green building community has been the most responsive. So I am very happy to have the opportunity to share the message about moving away from the use of halogenated flame retardants at Greenbuild.
The new LEED Pilot Credit on Chemical Avoidance for not using phthalates and halogenated flame retardants inside buildings should accelerate our progress towards healthier buildings.
BW:
You mentioned that this is also a chemical contamination problem that could have negative impacts on our health and well-being at a global level? How?
AB:
Many halogenated flame retardant chemicals are persistent and bioaccumulate especially in humans and animals high on the food chain. It is almost impossible to clean them up once they are out in the world. For example, PCBs, chlorinated chemicals that were also used as flame retardants, were banned in 1977, but very high concentrations can still be found in wildlife and some human populations today. Studies show that human breast milk contains flame retardants, and toddlers have three to four times higher body levels than their mothers.
When tested in animals, many halogenated flame retardants have been found to cause health problems like cancer, reduced fertility and IQ, thyroid disorders, and developmental impairment. Many halogenated flame retardants are also endocrine disrupting chemicals that can harm us at very low concentrations.
BW:
How do you weigh the known benefits today against long term unproven risks?
AB:
In furniture there is no proven benefit. It makes more sense to reduce the sources of ignition with fire-safe cigarettes and candles than to put potentially toxic chemicals in all the possibly flammable materials in our homes. Today the risk of home fires is diminishing due to a 50% decrease in cigarette consumption since 1980, enforcement of improved building, fire, and electrical codes, increased use of sprinklers and smoke detectors. These strategies provide measurable improvements in fire safety without toxicity.
Smoke and toxic gases kill people in fires, more than flames. Research on furniture fires show that while halogenated flame retardants can reduce the time for ignition by seconds, they greatly increase the carbon monoxide, smoke, and soot. The chemicals also release dioxin and related compounds when burned at relatively low temperatures. So the benefits of retarding the fire with toxic chemicals is greatly reduced by the increased fire toxicity and dioxins at the fire scene.
Given the lack of proven benefit in some cases, the risk-benefit calculation on chemical flame retardants can be tenuous even before you start to consider the widespread exposure to these chemicals on a daily basis.
Better methods of reducing fire risks include careful material selection and alternative fire suppression strategies that can be designed into products and buildings.
BW:
How can people take this knowledge and translate it into action?
AB:
When people know about the hazards of the flame retardants that are commonly used in many plastic foam insulations, furnishings and other building materials, they can choose alternative products or push for less toxic flame retardants. When green building professionals make these choices, this will increase the availability and decrease the cost of the alternatives.
Moving the market demand for flame retardants in the huge building sector can also help with policy changes. We have been providing scientific support to change a California furniture flammability standard to provide similar or greater fire safety without flame retardant chemicals.
We also need national chemical policy reform. Because of weaknesses in the Toxic Substances Control Act, which has not been updated since 1976, chemicals are innocent until proven guilty and that proof is almost impossible to obtain. Even asbestos could not be banned. And manufacturers are not required to perform any toxicity tests before putting chemicals into products! Green buildings need to be both energy-efficient and healthy. Reducing the use of halogenated flame retardants will help achieve this and help create a healthier world for us all.
HealthDid You Know…
Resource
…that some building products may expose you to the chemical banned from plastic bottles?
Everyone has heard the news about the health concerns associated with bisphenol A (BPA) leaching from baby bottles, food can liners and perhaps most famously those distinctive polycarbonate plastic water bottles popularized by Nalgene.[1] Last May, Chicago became the first city in the U.S. to ban the sale of baby bottles and sippy cups made from BPA. Few, however, are aware that BPA is a chemical component of epoxy resins used in a wide range of building materials, typically paints, sealants, adhesives and fillers,[2] that may put manufacturing workers, installers, and building occupants at risk.
Epoxy resins are used in building materials, often listed on a material safety data sheet as a proprietary mixture, without disclosure that the resin is made from BPA. While manufacturers claim that the BPA in epoxy resins is consumed entirely in the production process and does not show up in the final products, scientists investigating the metabolic breakdown of epoxy resins during occupational exposure have found that epoxy resin products can be metabolized in the human body back into BPA and may impact the endocrine and reproductive system of those exposed.[3]Animal studies have linked this hormone-disrupting chemical to prostate cancer, breast cancer, pre-diabetes (insulin resistance), abnormal fat metabolism, early puberty, and changes in the way the brain develops resulting in behavioral abnormalities.[4]
The BPA expert panel from the Center for Evaluation of Human Risks to Reproduction raised concern about BPA in epoxy-based resins, reporting to the National Toxicology Program that, “several studies collectively suggest hormonal effects of bisphenol A exposure, including one in occupationally exposed male workers likely exposed through multiple routes including inhalation…”[5] The NTP’s final monograph states that “a number of studies, when considered together, suggest a possible effect on reproductive hormones, especially in men exposed to higher levels of bisphenol A in the workplace.”[6] Germany has already instituted occupational exposure limits for bisphenol A.[7]
Recent biomonitoring studies have raised concerns about widespread human exposure to BPA. A National Health and Nutrition Examination Survey (NHANES) study found that more than 90% of people in a representative sample of the general population have BPA residues in their urine[8] and that there must be significant non-food exposures to reach such levels.[9]
It is likely that BPA in building products will become subject to greater health and safety regulation, but responsible specifiers do not need to wait for the regulatory system to catch up with the science to protect their clients. Products are available that can replace epoxy-based coatings and adhesives. For example, many paint companies now offer high-performance low-VOC water-based acrylic paints and acrylic-based adhesives for flooring, carpets, and wall covering. For applications where high-performance BPA-free substitutes are not yet available, the act of asking manufacturer reps for products without bisphenol A is an important step to prod the industry to bring safer high performance alternatives to market.
For a comprehensive discussion of the emerging science on BPA risks, read “Bisphenol A in Building Materials: High Performance Paint Coatings.”
SOURCES
- BPA is also known as a component of dental sealants, some medical and dental devices, and thermal paper receipts.
- Epoxy-based products are used in a wide range of applications including coatings (such as paints, floor sealers and protective coatings), adhesives and fillers (including caulks, grouts, mortars, and putties), fiberglass binders and cement additives. Epoxy resins are also in some wind energy applications, generators and other electronic equipment, industrial tooling applications, and materials used in the art, aerospace and marine industries.
- Hanaoka T, Kawamura N, Hara K, Tsugane S. Urinary bisphenol A and plasma hormone solvents in male workers exposed to bisphenol A diglycidyl ether and mixed organic solvents. Occupational and Environmental Medicine, 2002; 59:626; Cha B, Koh S, Park J, et. al. Influence of Occupational Exposure to Bisphenol A on the Sex Hormones of Male Epoxy Resin Painters. Mol Cell Toxicol. 2008; 4(3): 230-234.
- Sarah Janssen, staff scientist for the NRDC, summarizes health concerns and the issue with links to some of the key science on her 7/13/09 blog entry “California is the latest battleground on BPA regulation”. http://switchboard.nrdc.org/blogs/sjanssen/many_of_my_blog_posts.html.
- Expert Panel cited in NTP-CERHR Monograph on the Potential Human Reproductive and Developmental Effects of Bisphenol A page 15. http://cerhr.niehs.nih.gov/chemicals/bisphenol/bisphenol.pdf.
- Ibid at page 37.
- Murakami T, Oyama T, Isse T, et al. International comparison of criteria for evaluating sensitization of PRTR-designated chemical substances. Environmental Health and Preventive Medicine 2007;12:56–65, citing Deutsche Forschungsgemeinshaft. List of MAK and BAT Values 2004, Commission for the investigation of health hazards of chemical compounds in the work area, Report No. 40. Weinheim: Wiley-VCH Verlag GmbH & Co. KGaA; 2004.
- Calafat A., et. al., Urinary concentrations of bisphenol A and 4-nonylphenol in a human reference population. Environ. Health Persp. 2005; 113(4): 391-395. http://www.ehponline.org/members/2004/7534/7534.html. Accessed online June 20, 2009.
- Stahlhut R, Welshons W, Swann S. Bisphenol A data in NHANES suggest longer than expected half-Life, substantial nonfood exposure, or both. Environ Health Perspect. (2009); 117(5):784-789. http://www.ehponline.org/docs/2009/0800376/abstract.html. Accessed online July 20, 2009.
HealthDoubt Is Their Product
Resource
In Doubt Is Their Product, Dr. David Michaels, a former Assistant Secretary of Energy for Environment, Safety and Health under President Clinton, exhaustively documents the rise of the “product defense industry” and its strategy of using scientific discipline to establish controversies (i.e., starting something that is intended to continue or be permanent[1]), rather than establish facts (i.e., investigating something to confirm its truth or validity[2]) as a means of frustrating efforts to address public health risks from asbestos, benzene, aspirin (Reye’s syndrome in children), global warming and, of course, vinyl.
“Doubt is our product,” wrote a Brown and Williamson[3] executive in 1969, three years after the iconic warning label first appeared on cigarette packs, “since it is the best means of competing with the ‘body of fact’ that exists in the minds of the general public. It is also the means of establishing a controversy.”[4]
Michaels concentrates his reporting on his considerable first-hand experiences where, he writes, “I had the opportunity to witness what is going on at close range.”[5] He bears witness for 256 pages and backs up his observations with an additional 119 pages of endnotes, many of these referencing original documents that can be accessed through his website, www.defendingscience.org.
One of his first-hand experiences involves polyvinyl chloride plastic, also known as PVC or vinyl. The story of the vinyl industry’s cover-up of rare cancers among its workers in the mid-1970’s has been well documented elsewhere[6], including the documentary Blue Vinyl and the PBS investigative report Trade Secrets. Michaels connects the dots, documenting how, in 1974, the same public relations firm that created the “selling doubt” strategy for the tobacco industry would “establish uncertainty” about the risks of vinyl chloride for the PVC industry. They’re still at it.
Doubt Is Their Product concludes with a chapter offering “a dozen ways to improve our regulatory system.” Many of these could be adapted by green building policy makers or by anyone interested in testing whether an industry stakeholder is interested in establishing the facts, or just establishing a perpetual controversy.[7]
SOURCES
- Encarta® World English Dictionary ©1999 Microsoft Corporation.
- Ibid.
- Brown & Williamson was an American tobacco company and subsidiary of the giant British American Tobacco, that produced several popular cigarette brands including: Kool, Lucky Strike, Pall Mall and Viceroy. It became infamous as the focus of investigations for chemically enhancing the addictiveness of cigarettes. Its former vice-president of research and development, Jeffrey Wigand, was the whistleblower in an investigation conducted by the highly respected CBS news program 60 Minutes, an event that was dramatized in the film The Insider. Wigand claimed that B&W had introduced chemicals such as ammonia into cigarettes to increase nicotine delivery and increase addictiveness. Brown & Williamson had its headquarters at Louisville, Kentucky until July 30, 2004, when the U.S. operations of Brown & Williamson merged with R.J. Reynolds, creating a new publicly traded parent company, Reynolds American Inc. Source: http://en.wikipedia.org/wiki/Brown_and_Williamson.
- Doubt Is Their Product, p. 11, footnote 43, document available at http://legacy.library.ucsf.edu/tid/nvs40f00.
- Doubt Is Their Product, Introduction, p. x.
- See, e.g. Deceit and Denial: The Deadly Politics of Industrial Pollution. Gerald Markowitz and David Rosner. University of California Press, 2002. See also Toxic Sludge is Good For You and Trust Us We’re Experts, both by John Stauber and Sheldon Rampton, and The Republican War on Science, by Chris Mooney.
- These include e.g., (#1) Require full disclosures of any and all sponsor involvement in scientific studies; (#3) Manufacturers must disclose what they know about the toxicity of their products; (#5) Hold real people accountable for the accuracy—and completeness – of statements of corporations and trade groups.
HealthStudy Finds Vinyl Plasticizers a Major Contaminant in Household Dust
Resource
Chemicals From Common Products Create “Toxic Cocktail” in Homes
Toxic chemicals common to home furnishings and electronic equipment have been found in household dust, including chemicals internationally recognized as harmful or toxic to the immune and reproductive systems; babies and young children are particularly at risk from exposure. That is the finding of a 2005 report, Sick of Dust: Chemicals in Common Products, which investigated six classes of chemicals in dust samples taken from 70 homes in seven states across the U.S. Among the chemicals documented in household dust are two — phthalate plasticizers and organotin stabilizers — that are ubiquitous in PVC vinyl building materials.
Over 90%
of phthalates manufactured are used in PVC products, and have been documented as leaching from shower curtains and flooring.
Animal studies have found phthalates disrupt reproductive systems, particularly in male offspring, and can contribute to male infertility. Phthalates have also been linked to asthma and respiratory problems in children.
Organotins, which are found in PVC water pipes, PVC food packaging materials, and many other consumer products, are poisonous in even small amounts, and can disrupt the hormone, reproductive, and immune systems.
In addition to the two chemicals commonly associated with PVC building materials, the report also found high concentrations of brominated flame retardants, which are incorporated into many plastics, including PVC, and electrical goods. Studies have revealed the breast milk of American women has 10 to 100 times higher concentration of PBDE, a type of flame retardant, than European women. According to Sick of Dust, a recent study indicates that levels of PBDE in Swedish breast milk began to decrease in 1997, possibly due to a voluntary phase-out of penta-DBE.
These findings add to the momentum of an anti-PVC movement which, according to a feature article in the Christian Science Monitor, is “picking up steam,” and provide additional ammunition for the many commenters who took aim at the USGBC’s draft PVC report that found “PVC does not emerge as a clear winner or loser.”
The Sick of Dust report ranks brand name companies and retailers on their use of hazardous chemicals, and provides an outline of fundamental changes needed to bring American chemical regulation up to a level that will protect basic health today and in future generations. But the easiest way to eliminate phthalates and organotins from household dust is to eliminate PVC from the household.