As noted in Healthy Building Network’s(HBN) Chlorine and Building Materials report, chlorine production is a major source of releases of carbon tetrachloride, a potent global warming and ozone depleting gas as well as a carcinogen.
As the report reminds us, it’s important to consider not only the use-phase impacts of building products, but the entire life cycle, including primary chemical production that’s several steps back from final product manufacture.
Blowing agents are used in plastic foam insulation to create the foam structure and also contribute to the insulative properties. Over the years, manufacturers have cycled through a range of fluorocarbons as each prior class is phased out due to environmental concerns – from ozone depleting chlorofluorocarbons (CFCs) to less ozone depleting hydrochlorofluorocarbons (HCFCs) to the non-ozone depleting but high global warming potential hydrofluorocarbons (HFCs) currently common in many types of foam insulation. Manufacturers have now begun the latest shift to next generation, low global warming potential hydrofluoroolefins (HFOs). For extruded polystyrene (XPS), this translates to a shift from commonly used HFC-134a with a global warming potential (GWP) of 1,430 to HFO-1234ze with a GWP of six.2
The summary of these chemical transitions only tells part of the story. While HFOs do not directly deplete the ozone layer or significantly contribute to global warming, many HFOs use carbon tetrachloride (CCl4) as a chemical feedstock. This includes HFO-1234ze, the replacement for HFC-134a (which does not use CCl4) in many applications.3
How is it that this ozone depleting substance is still in use? Many uses of carbon tetrachloride were phased out in 1995, under the terms of the Montreal Protocol to protect the ozone layer. But the Montreal Protocol phase-outs exempted the use of CCl4 as a chemical feedstock, under the assumption that emissions would be minor.4 However, carbon tetrachloride “is not decreasing in the atmosphere as rapidly as expected” based on its known lifetime and emissions, according to a 2016 report on the Mystery of Carbon Tetrachloride. The authors of this report concluded that emissions of carbon tetrachloride during its production, and fugitive emissions from its use as a chemical feedstock, have been significantly unreported and underestimated.5
Production of carbon tetrachloride is likely to increase as industry replaces HFC blowing agents (and refrigerants), most of which aren’t produced with carbon tetrachloride, with HFOs that do use CCl4 as a feedstock.[6] With increased production and use of carbon tetrachloride, increased emissions are expected – and that’s bad news for the earth’s recovering ozone layer.
We recommend against the use of plastic foam insulation whenever possible, but if you do use it, some products are available that use other, less impactful, blowing agents, including hydrocarbons and water. For more recommendations about preferable insulation from a health hazard perspective, review our product guidance at informed.habitablefuture.org.
The Home Depot Chemical Strategy, included in its 2017 Responsibility Report, targets a range of chemicals known or suspected to cause cancer, mimic and disrupt hormone systems, and impair brain function. The retailer’s policies, for certain product categories, far exceed the chemical restrictions of LEED and most product certifications in these categories. The world’s largest retailer of building products credited HBN’s “guidance on priority chemicals and innovation” as it adopted many of the recommendations made by HBN and other environmental health groups in a dialogue begun in 2014.
By applying its chemical strategy to all products in target categories, Home Depot makes important strides toward equity in the green building movement. It tracks many of the recommendations HBN provides to the affordable housing community in our HomeFree initiative. Because it impacts products at all price points, not just premium products and not just those that qualify for the retailer’s Eco-Options program, the policy ensures that all contractors and do-it-yourself customers get healthier products regardless of the brand purchased, and regardless of whether or not the product has been certified “green.” One of the qualifying products, a flat sheen paint, is the first “zero VOC” paint priced under $20 per gallon.[1] “We’re not just sourcing new healthier products, we are striving to improve our current assortment of the products we already sell,” Ron Jarvis, Home Depot Vice President of Merchandising and Sustainability, told HBN.
Home Depot’s most significant advances are in reducing toxic hazards in carpets and paints. The new carpet policy implements two major recommendations of HBN’s newest report, Eliminating Toxics In Carpet: Lessons For The Future of Recycling. published last week. As we reported, Shaw Industries – the country’s largest carpet manufacturer – recently stopped using fly ash from coal-fired power plants as filler. Today, Home Depot announced that fly ash, which contains toxic heavy metals, is “excluded from indoor wall-to-wall carpet in our U.S. and Canada stores.” Home Depot also announced its carpet does not contain several other chemicals that HBN has prioritized for elimination, including ortho-phthalates and organotins used in carpet backings.
Home Depot will also eliminate a class of toxic chemicals from paints called alkylphenol ethoxylates (APEOs). These chemicals, which are present even in low VOC paints, are surfactants, which help different types of material mix together well, and are coming under increased scrutiny as hormone disrupting chemicals with health effects ranging from breast cancer, reproductive disorders and obesity. They are mostly phased-out in Europe and Japan, but still common in the U.S., even though the EPA has identified over 200 “safer surfactants” to replace them.[2]
Today’s announcement is the next step on a long road that started with Home Depot’s 2015 move to eliminate phthalates from vinyl flooring. Much work lies ahead. For example, the company noted that it was not removing methylene chloride paint strippers from its shelves, a major objective of the national consumer campaign Mind The Store. The retailer’s hazard avoidance policy does not address some important problems even within the building product categories in its scope, and does not apply to many other high-impact building product categories. Regrettably, full public disclosure of all product ingredients is not required.
However, the hazard avoidance approach of the Home Depot Chemical Strategy signals fundamental, permanent and systemic improvement in the building products industry, and is a strong step towards health equity in building products. It leans toward a future when “healthy products” are not sold for a premium or as specialty items, and any product on the shelf meets the reasonable consumer expectations that it is healthy for people and our planet.
The Home Depot 2017 Responsibility Report can be found here:
https://corporate.homedepot.com/newsroom/infographic-2017-responsibility-report
Healthy Building Network’s report on post-consumer carpet feedstocks calls for eliminating over 40 highly toxic chemicals in carpets that threaten public health and impede recycling. These toxics are known to cause respiratory disease, heart attacks, cancer, and asthma, and impair children’s developmental health.
The report outlines strategies to protect public health and the environment by improving product transparency, eliminating dangerous chemicals from carpets, and increasing carpet recycling rates. It also reveals surprising efforts in the industry to remove many of these toxic substances from carpet design.
Building products incorporating antimicrobial additives are becoming increasingly prevalent. Paints, and other touchable surfaces such as countertops, and virtually any product considered as an interior finish may contain one or a combination of antimicrobials. These agents are considered pesticides, but their identity—and related hazards—can be difficult for the average person to discover. This lack of transparency creates a hurdle for the informed selection of products with reduced negative impacts.
No evidence yet exists to demonstrate that products intended for use in interior spaces that incorporate antimicrobial additives actually result in healthier populations. Further, antimicrobials may have negative impacts on both people and the environment. This paper, prepared by Perkins&Will in partnership with HBN, aims to present current information about reported or potential health and environmental impacts of antimicrobial substances as commonly used within the building industry, and to assist architects, designers, building owners, tenants, and contractors in understanding those impacts.
In response to growing concerns over COVID-19, Healthy Building Network (HBN) and global architecture and design firm Perkins and Will reexamined and reaffirmed the conclusions and recommendations of this white paper.
Asphalt (also known as asphalt concrete, bitumen, or road tar) is the most common paving material by far, accounting for a 92 percent share of the 2.5 million miles of roads and highways in the United States. Reclaiming and reusing asphalt has many benefits, including waste prevention, reduction of greenhouse gas emissions, and lower lifecycle impacts compared to virgin asphalt material use.
Keys to increasing the recycling of asphalt and its attendant environmental benefits include simplifying the designs of asphalt mixes, reducing toxic additives in production, tracking materials from production through use and recycling, testing incoming materials for contaminants, and avoiding the addition of cutback solvents and other toxic rejuvenating agents.
Research from Healthy Building Network (HBN) documents how vinyl building products, also known as PVC or polyvinylchloride plastic, are the number one driver of asbestos use in the US.
The vinyl/asbestos connection stems from the fact that PVC production is the largest single use for industrial chlorine, and chlorine production is the largest single consumer of asbestos in the US. [1] More than 70% of PVC is used in building and construction applications – pipes, flooring, window frames, siding, wall coverings and membrane roofing. [2] This makes the building and construction industry the single largest product sector consuming chlorine, bearing sizeable responsibility for the ongoing demand for asbestos. [3]
Despite the existence of asbestos (and mercury) free chlorine production methods, the PVC industry has positioned itself at the vanguard of industry efforts to frustrate stronger asbestos regulation. According to Mike Belliveau, the Executive Director of the Environmental Health Strategy Center and a senior advisor to Safer Chemicals Healthy Families coalition, “The PVC market has spurred chemical industry lobbyists to urge the Trump Administration to exempt their use of deadly asbestos from future restrictions.” The last time the vinyl industry positioned themselves so publicly on the other side of common sense, they were defending the use of lead in children’s vinyl lunch boxes.
The health hazards of asbestos exposure, painful and deadly lung diseases including cancer, are clear. Green building professionals do not have to wait. Do your part to prevent asbestos-related diseases here and abroad. Don’t specify vinyl building products.
1. In the US more than half of chlorine is produced using asbestos, despite the availability of an alternative production method that does not require either asbestos or mercury.
2. http://www.vinylinfo.org/vinyl/uses
3. According to IHS Markit, “A majority of chlor-alkali capacity is built to supply feedstock for ethylene dichloride (EDC) production. EDC is then used to make vinyl chloride (VCM) and subsequently used to manufacture polyvinyl chloride (PVC). This chain, EDC to VCM to PVC, is normally called the vinyl chain. PVC demand correlates closely with construction spending, therefore, it can be concluded that chlorine consumption and production are driven by the construction industry. Hence, chlorine consumption growth depends on the growth of the global economy, since a country will spend more on construction if it has a healthy gross domestic product.” (IHS Markit. “Chemical Economics Handbook: Chlorine/Sodium Hydroxide (Chlor-Alkali),” December 2014. https://www.ihs.com/products/chlorine-sodium-chemical-economics-handbook.html)
4. Fifteen chlor-alkali plants last reported to be using asbestos diaphragms include, in order of estimated chlorine capacity:
5. Carpentier, Steve. “Minaçu, a cidade que respira o amianto.” CartaCapital, May 21, 2013. http://www.cartacapital.com.br/sustentabilidade/minacu-a-cidade-que-respira-o-amianto-8717.html
Healthy Building Network’s research into current recycling practices for flexible polyurethane foam (FPF) indicates that most post-consumer feedstocks are contaminated with highly toxic flame retardants.
Discussions of recycling FPF have centered around the human health and environmental hazards posed by the flame retardant PentaBDE, which the foam industry phased out a decade ago. But the flame retardants that have replaced PentaBDE present similar concerns. Manufacturers incorporate flame retardant-laden post-consumer FPF into new products, primarily bonded carpet cushion. Recycling and installation workers and building occupants, particularly crawling children, can be exposed to these toxic chemicals. The recent emergence of pre-consumer FPF scrap that is free of flame retardants is a great step toward a safer, more valuable feedstock, but more work is needed to track and label flame retardant-free FPF to ensure that future post-consumer foam is also flame retardant-free.
Polyethylene is the world’s most common plastic. It is used in packaging, food and beverage containers, and consumer products.
Building product manufacturers sometimes use post-consumer recycled polyethylene bags and bottles in pipes and plastic lumber. This scrap usually has minimal contents of concern, but products like detergents stored in plastic packaging can remain. So-called “bio-degradation” agents in plastic bags also contaminate this feedstock and should never be used. The plastics recycling industry is developing protocols to screen out residual contaminants. Of greatest concern: Most polyethylene goes unrecycled in the United States due to problems in supply chain controls and the low price of virgin resins. This report examines ways to optimize the use of post-consumer polyethylene in building materials.
Not all recycled content materials are created equal – especially when it comes to recycled plastics.
In a report released by StopWaste and the Healthy Building Network, we take an in-depth look at the health implications, supply chain considerations, and potential to scale up recycling of the world’s most common plastic: polyethylene (aka PE). [1] This report, Post-Consumer Polyethylene in Building Products, is the latest installment in our Optimizing Recycling series.
Polyethylene is a material widely used in product packaging, beverage containers, and myriad consumer products. High Density Polyethylene (HDPE), Low Density Polyethylene (LDPE), and Linear Low Density Polyethylene (LLDPE) are all readily recyclable in California. Polyethylene plastic scrap bottles and plastic bags usually have minimal contents of concern and are easily processed into feedstock for new products, including building materials. Despite the great potential for recovery of PE, sizeable barriers stand in the way of a lot more recycling.
The explosive growth in virgin ethylene production on the U.S. Gulf Coast, driven by cheap energy, has meant that most post-consumer scrap PE is either landfilled, incinerated, or sent overseas for processing. [2]
Industry trends in recycling collection technology are also undermining the value of post-consumer polyethylene feedstocks. Pipe and plastic lumber manufacturers in the U.S. require supplies that have minimal amounts of contaminants such as volatile residual substances in packaging and other types of plastics. Yet proportionally less “good material” is coming out of the plastic waste recycling stream due to the rising use of municipal single stream recycling over the past decade. Mixed and low quality scrap materials that come from single-stream recycling centers are more likely to be exported than sorted and screened for high-quality polyethylene scrap. As a result, more recovered plastic bags are exported than processed domestically. [3]
Additives used for plastics can turn into contaminants when recycled. As seen with other recycled content materials, feedstocks with less contamination have an increased potential for recyclability as well as increased value to purchasers. [4] For PE, contaminants come in the form of residual materials from packaging (residue from bottles that contained pesticides, for example), or from additives used in manufacturing to achieve certain product characteristics. Perhaps the most problematic additive to PE products are so-called biodegradation additives used in plastic packaging. These additives (but not the rest of the plastic) degrade when exposed to sunlight or other environmental conditions. When these products are collected and used as post-consumer recycled feedstocks in products like pipes and decking, however, these additives can lower the reliability and value of a manufacturer’s product. This is why, in our report, we recommend that plastic manufacturers stop using degradability additives in all new polyethylene.
A half-century ago, the federal government started regulating solid wastes and preventing rampant dumping in the woods, ocean, and unlined dumps. Then the so-called Not-In-My-Backyard (NIMBY) movement of the 1970s and 1980s prevented scores of landfills and incinerators from being permitted across the country, just as existing disposal sites were reaching capacity. There were also spectacular failures at waste sites that made headlines. Coal ash ponds failed, releasing contaminated waste into rivers and drinking water. Giant piles of tires caught on fire, and came to symbolize the crisis of growing piles of waste.
In response, environmental agencies partnered with waste generators like the coal power and tire industries to find ways to reduce the amount of their wastes going to landfills. The US Environmental Protection Agency developed an option called “beneficial use,” in which these wastes could be diverted to build roads, fill old mines, and turn wastelands into golf courses. Some of these “beneficial uses” hit literally close to home; coal waste has been diverted into wallboard and carpet backing, tires into flooring, and contaminated soils into our own backyards, without any regulation.
“On Tire Wastes in Playgrounds” reveals how chopped up tire mulch is becoming as common as dirt in playgrounds, and why government health agencies are beginning to take action to protect children from exposure to toxic substances in the rubber waste, like polycyclic aromatic hydrocarbons and lead.
“Filled with Uncertainty: Toxic Dirt in Building & Construction” examines the unregulated dirt trade. Our research found that soil and coal ash contaminated with neurotoxic substances have become commonplace construction materials, from structural fill to flower bed topsoil. Contaminated material is often sold as “clean fill” by untrustworthy companies. With no tracking in place, building owners have no idea, and probably don’t think to ask, where their fill is coming from.
Waste has a way of finding the path of least resistance. A void of oversight coupled with numerous government and private sector incentives promoting the use of unregulated recycled content leaves it to responsible architects, designers, contractors and building owners to increase scrutiny of this vast diversion of wastes into our homes, schools, playgrounds and places of business. In the absence of political will, building owners and residents are left to protect themselves. We hope these articles will lead developers, especially of residential areas and playgrounds, to start asking more questions of dirt and fill contractors, beginning with: where did your materials come from, and have they been tested for toxic contaminants?