Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.
Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.
Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.
Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.
Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.
Update! HEALTHY BUILDING NETWORK IS NOW HABITABLE.

“To protect the health of our state’s children,” California Governor Arnold Schwarzenegger signed legislation on October 14, 2007 prohibiting the use of phthalates (pronounced “thall-eights”) in childcare products designed for babies and children under three years of age.

Phthalates are used as plasticizers to soften polyvinyl chloride plastic, also known as PVC or vinyl, including a wide range of building products such as vinyl flooring, wallcovering and upholstery.

Phthalate plasticizers are not chemically bound to PVC. They have been found to leach, migrate or evaporate into indoor air and atmosphere, foodstuff, IV solutions and other materials, etc. Consumer products containing phthalates can result in human exposure through direct contact and use, indirectly through leaching into other products, or general environmental contamination. Humans are exposed through ingestion, inhalation, and dermal exposure during their whole lifetime, starting in the womb. Phthalates come in many different formulas. Most haven’t been tested or examined at all for human health impacts. The Consumer Product Safety Commission has noted that one phthalate formula common to certain building materials — DINP [1] — is a mixture of up to 100 chemical variants, of which only five have been minimally studied [2]. Others have been found to pose a risk of serious negative health impacts at very low doses.

Phthalates have been shown to have negative effects on human health including interference with the natural functioning of the hormone system, and reproductive and genital defects. Phthalates may lower sperm count and are associated with the risk factors for testicular cancer, as well as early onset of puberty and premature birth.

In June 2005, HBN discussed recent research findings that the cumulative impact of different phthalates leads to an exponential increase in associated harm, and documented levels of phthalates found in humans at levels higher than levels shown to cause adverse health effects. A 2007 study concluded that the exposure of children to phthalates exceeds that in adults, warning, “Current human biomonitoring data prove that the tolerable intake of children is exceeded to a considerable degree, in some instances up to 20-fold” [3].

Phthalates have been found in high quantities in studies of household dust. Other studies have documented links between childhood asthma and phthalate exposure from vinyl flooring. Because phthalates are not a volatile organic compound (VOC), however, they are usually not accounted for by indoor air quality standards such as those used to certify green building materials.

California now joins the EU [4] in restricting the use of phthalates in the use of children’s products, and many other US states are expected to take up legislation similar to that signed by Governor Schwarzenegger [5].

Like the human carcinogens vinyl chloride and dioxin, phthalates are uniquely associated with PVC [6]. It is this triple threat from PVC that distinguishes it as the worst plastic for environmental health and green building. Regrettably, there are still few restrictions on the use of vinyl in green buildings.

SOURCES

  1. Diisononyl phthalate, a general use vinyl plasticizer. It is the primary plasticizer used in vinyl toys, though it finds many other applications such as garden hoses, shower curtains, vinyl flooring and wall covering. Source: http://www.phthalates.org/glossary.asp [link no longer available]
  2. “Aggregate Exposures to Phthalates in Humans,” Health Care Without Harm, July 2002. http://www.noharm.org/lib/downloads/pvc/Agg_Exposures_to_Phthalates.pdf, p.16, footnote 149 Heudorf et al., 2007. “Phthalates: Toxicology and exposure“. International Journal of Hygiene and Environmental Health. Article in Press.
  3. Heudorf et al., 2007. “Phthalates: Toxicology and exposure“. International Journal of Hygiene and Environmental Health. Article in Press.
  4. “Permanent EU ban on phthalates in toys and childcare articles is published” TDCTrade.com website, Feb 03, 2006, http://www.hktdc.com/info/mi/a/baeu/en/1X008GDB/1/Business-Alert-%E2%80%93-EU/Permanent-EU-ban-on-phthalates-in-toys-and-childcare-articles-is-published.htm
  5. “A nationwide toxic toy ban likely to follow state lead” SF Chronicle, October 16, 2007, http://www.sfgate.com/cgi-bin/article.cgi?file=/c/a/2007/10/16/MNT0SQDJV.DTL
  6. About 80 to 90% of phthalate production goes into PVC (Costner, Pat et al. 2005, “Sick of Dust: Chemicals in Common Products–A Needless Health Risk in Our Homes”, Safer Products Project, http://safer-products.org/downloads/Dust Report.pdf and the Phthalates Information Centre Europe http://www.phthalates.com

A week after the US Green Building Council’s (USGBC) Technical Science Advisory Committee determined that PVC was one of the most unhealthy building materials in part due to occupational exposures to vinyl chloride, the federal Chemical Safety Board (CSB) found that a massive release of vinyl chloride led to the explosion that killed 5 workers at a PVC factory in Illiopolis, Illinois on April 23, 2004.

The CSB Investigation Report is made all the more relevant to green building professionals in light of the USGBC’s finding that PVC flooring ranked absolute worst in both human health and environmental factors compared to the alternatives reviewed. The destroyed factory, owned by Formosa Plastics, had been a major supplier of vinyl resin for Armstrong floors.

The CSB is the industrial equivalent of the National Transportation Safety Board (NTSB), the agency that rushes investigators to the scene of plane crashes, train derailments and the like. [1] The CSB’s March 6, 2007 report found among other things that the cause of this accident, “inadvertently draining a reactor, is a serious hazard in the PVC manufacturing process.” [2] Indeed just 60 days before the fatal explosion, workers at the same facility accidentally released an undisclosed amount of vinyl chloride. The report also notes that 8,000 pounds of vinyl chloride were released by accident in June 2003 at the company’s Baton Rouge, LA facility. [3] A year after the explosion, in May 2005, another 2,500 pounds of vinyl chloride were accidentally released from the company’s Delaware City, DE location. [4] Each release was caused by the same problems which led to the catastrophe at the Illiopolis facility in April 2004. Other PVC factories owned by Formosa have also suffered catastrophic explosions in the recent past. [5]

The chemical at issue, vinyl chloride, is a human carcinogen whose total danger is believed by many to be underestimated by the EPA. A 2005 study in the peer reviewed journal American Health Perspectives found that the EPA employed discredited scientific practices at the behest of the chemical industry in order to lower estimates of vinyl chloride’s cancer potency by tenfold. [6]

The USGBC’s study of PVC found it “consistently among the worst materials for human health impacts” based upon exceedingly conservative estimates of impact. To understand how conservative, consider that its evaluation of PVC only accounted for exposures from normal operations to workers in the factory and neighbors at the fenceline. The health impacts of the extraordinary accidental releases from Formosa’s facilities described above — and the deadly explosions that can follow as at Illiopolis — are beyond the reach of tools like LCA and risk analysis.

This CSB report further underscores the significance of the USGBC’s decision to be guided by the Precautionary Principle in its evaluation of green building materials and to fully consider the impacts of manufacturing processes on production workers. It is the essence of precaution to avoid hazards and risks that are avoidable. So remember this the next time you specify pipe, roofing membranes, wall coverings and especially flooring: the chemical that killed those 5 men in Illiopolis is essential and unique to only one material you are considering: PVC plastic, also known as vinyl. [7]

SOURCES

  1. The CSB is an independent federal agency charged with investigating industrial chemical accidents. The agency’s board members are appointed by the president and confirmed by the Senate. CSB investigations look into all aspects of chemical accidents, including physical causes such as equipment failure as well as inadequacies in regulations, industry standards, and safety management systems. The Board does not issue citations or fines but does make safety recommendations to plants, industry organizations, labor groups, and regulatory agencies such as OSHA and EPA.
  2. US Chemical Safety and Hazard Investigation Board Investigation Report, Formosa Plastics Corp., Illiopolis, Illinois, April 23, 2004 p. 29. http://www.csb.gov/completed_investigations/docs/FormosaPlasticsIlliopolisReport.pdf
  3. Ibid. p. 28
  4. Ibid. p. 29
  5. http://abclocal.go.com/wpvi/story?section=nation_world&id=3514274 [link no longer available]
  6. Jennifer Beth Sass, Barry Castleman and David Wallinga. “Vinyl Chloride: A Case Study of Data Suppression and Misrepresentation,” Environmental Health Perspectives, published online 24 March 2005, doi:10.1289/ehp.7716, http://www.ehponline.org/members/2005/7716/7716.html
  7. To be sure, vinyl chloride is not the only avoidable risk in the production of flooring, or plastics, or materials generally. However, the risk of explosion is only one of the negative environmental health consequences of vinyl chloride whose use is both essential and unique to PVC plastic. Related impacts include dioxin emissions from manufacture and fire, the use and release of toxic additives such as cadmium and lead stabilizers and phthalate softeners, and the threats associated with the production of massive quantities of chlorine gas as the basic building block of vinyl chloride production. These factors lead HBN to the conclusion that PVC is the worst plastic for the environment.

Chemicals From Common Products Create “Toxic Cocktail” in Homes

Toxic chemicals common to home furnishings and electronic equipment have been found in household dust, including chemicals internationally recognized as harmful or toxic to the immune and reproductive systems; babies and young children are particularly at risk from exposure. That is the finding of a 2005 report, Sick of Dust: Chemicals in Common Products, which investigated six classes of chemicals in dust samples taken from 70 homes in seven states across the U.S. Among the chemicals documented in household dust are two — phthalate plasticizers and organotin stabilizers — that are ubiquitous in PVC vinyl building materials.

Over 90%

of phthalates manufactured are used in PVC products, and have been documented as leaching from shower curtains and flooring.

Animal studies have found phthalates disrupt reproductive systems, particularly in male offspring, and can contribute to male infertility. Phthalates have also been linked to asthma and respiratory problems in children.

Organotins, which are found in PVC water pipes, PVC food packaging materials, and many other consumer products, are poisonous in even small amounts, and can disrupt the hormone, reproductive, and immune systems.

In addition to the two chemicals commonly associated with PVC building materials, the report also found high concentrations of brominated flame retardants, which are incorporated into many plastics, including PVC, and electrical goods. Studies have revealed the breast milk of American women has 10 to 100 times higher concentration of PBDE, a type of flame retardant, than European women. According to Sick of Dust, a recent study indicates that levels of PBDE in Swedish breast milk began to decrease in 1997, possibly due to a voluntary phase-out of penta-DBE.

These findings add to the momentum of an anti-PVC movement which, according to a feature article in the Christian Science Monitor, is “picking up steam,” and provide additional ammunition for the many commenters who took aim at the USGBC’s draft PVC report that found “PVC does not emerge as a clear winner or loser.”

The Sick of Dust report ranks brand name companies and retailers on their use of hazardous chemicals, and provides an outline of fundamental changes needed to bring American chemical regulation up to a level that will protect basic health today and in future generations. But the easiest way to eliminate phthalates and organotins from household dust is to eliminate PVC from the household.

To breathe, I have to take way too many medicines today – each with their side effects.

I’m an adult. Imagine a child having to wade through all the symptoms and medicines associated with asthma.

Many factors contribute to the development and aggravation of asthma. However, I am wondering whether the installation of PVC flooring in my bathroom and kitchen contributed to the worsening of my breathing.

The floor was laid three years ago. A slow leak under my sink went unnoticed until the downstairs’ neighbor’s ceiling fell. About this time, my life-long respiratory ailments worsened.

Scientists are investigating the relationship between moisture, PVC flooring, and asthma.

In Sweden, a study of 10,851 children found the presence of both floor moisture and PVC significantly increased the risk of asthma.[1] The incidences were higher in multiple family dwellings where a higher percentage of PVC flooring was found.

Many workers in an office building in Finland, over a short period of time, were diagnosed with adult-onset asthma at a rate of about 16 times higher than expected.[2] An investigation uncovered in the office air space high levels of volatile chemicals, such as 2-ethyl-l-hexanol, l-butanol, which are degradation by-products of vinyl. The problem was traced back to damp concrete surfaces below the PVC flooring.

The PVC flooring was removed and surface of the concrete slab warmed up enough to remove the volatiles that had been diffused within. In rooms cleaned up in this manner and floors replaced with ceramic tile, the emissions of the three main volatiles (2-ethyl-l-hexanol, l-butanol, and 3-heptanone) decreased, as did employees’ symptoms and many asthma patients’ needs for medication.

Furthermore, studies have linked dust containing phthalates from homes with PVC flooring with an increase in asthma.

To make it less brittle, PVC is coated with plasticizers called phthalates. These chemicals evaporate and enter the air space where they adhere to dust particles.[3] New research shows that dust from homes containing PVC floors has higher levels of phthalates – particularly di(2-ethylhexyl) (DEHP) – than dust from homes without vinyl floors. One recent case-control study found an association between dust concentrations of phthalates inside homes and asthma, rhinitis and eczema.[4] The presence of PVC flooring in the child’s bedroom was the strongest predictor of respiratory ailments.

Other studies reach similar conclusions,[5] with one recommending “avoidance of PVC flooring in homes with small children” as a simple first step.[6]

Avoiding PVC flooring isn’t difficult, but it’s often disregarded as a cost-cutting measure.

Meanwhile, the costs associated with the increase in rates of asthma keep adding up. According to officials in my home state of Massachusetts, asthma is the number one preventable cost to hospitals.[7]

Prescription costs, doctors’ fees, lost wages due to time off from work for parents of asthmatic children, and the un-quantifiable cost of school absenteeism add up to a hefty burden for families and society.

Alternatives to PVC that are easier on the lungs exist today.

By switching to safer products we could be offering a child the priceless gift of easy breathing.
Guest columnist Niaz Dorry is a veteran activist and writer living in Gloucester, Massachusetts. She works with small-scale, traditional, and indigenous fishing communities in the U.S. and from around the globe to advance the rights and ecological benefits of the small-scale fishing communities as a means of protecting global protect marine biodiversity. In 1998, Time Magazine named Niaz as a Hero For The Planet for this work. Her fisheries articles appear regularly in a range of publications.

SOURCES

  1. Bornehag, C.G., Sundell , J., Hägerhed , L., Janson, S., and the DBH-study group, “Dampness In Buildings And Health. Dampness At Home As A Risk Factor For Symptoms among 10 851 Swedish Children” (DBH-STEP 1) (2002), SP Swedish National Testing and Research Institute and the International Centre for Indoor Environment and Energy, Technical University of Denmark Karlstad University, Sweden.
  2. Tuomainen, A., Seuri, M., Sieppi, A. “Indoor Air Quality And Health Problems Associated With Damp Floor Coverings In An Office Building” (2002), Kuopio Regional Institute of Occupational Health, Department of Occupational Hygiene and Toxicology, Kuopio, Finland; Kuopio Regional Institute of Occupational Health, Department of Occupational Medicine, Kuopio, Finland; and, Medivire Occupational Health Center, Kuopio, Finland.
  3. Katherine M. Shea, MD, MPH, and the Committee on Environmental Health; “Pediatric Exposure and Potential Toxicity of Phthalate Plasticizers.” Technical Report. American Academy of Pediatrics. PEDIATRICS Vol. 111 No. 6 June 2003.
  4. Carl-Gustaf Bornehag, Jan Sundell, Charles J. Weschler, Torben Sigsgaard, Björn Lundgren, Mikael Hasselgren, Linda Hägerhed-Engman, “The Association Between Asthma and Allergic Symptoms in Children and Phthalates in House Dust: a Nested Case-Control Study, Environmental Health Perspectives, July 15, 2004 (The National Institute of Environmental Health Sciences, National Institutes of Health, U.S. Department of Health and Human Services).
  5. Ruthann Rudel and Julia G. Brody, Silent Spring Institute, Newton MA; David Camann, Southwest Research Institute, San Antonio, TX; John Spengler, Harvard School of Public Health, Boston, MA; Leo Korn, UMDNJ, New Brunswick, NJ, “Phthalates, Alkylphenol, Pesticides, Polybrominated Diphenyl Ethers, and Other Endocrine Disrupting Compounds in Indoor Air and Dust,” Environmental Science & Technology, September 13, 2003.
  6. Haumann , T. and Thumulla, J., “Semi Volatile Organochemicals In Indoor Environment – Chlorinated Phosphorus And Organotin Compounds In Material Und House Dust Samples” (2002) Umweltanalytik und Baubiologie, Essen, Germany. AnBUS e.V., Fürth, Germany.
  7. Remarks of Massachusetts Division of Health Care Finance Policy official at the Massachusetts Department of Public Health’s conference on asthma, March 23, 2002.

Hyperbole? No.

PVC manufacturing consumes in excess of 40 per cent of the chlorine gas produced in this country, making it the nation’s single largest user of the deadly chemical. By comparison, 5 percent of the nation’s chlorine gas is used to disinfect water – and that includes sewage treatment.

Chlorine gas kills and maims in a manner so heinous that it was banned as a chemical weapon after the battlefield experiences of World War I. Today, according to the Washington Post, anti-terrorist experts say there is “little doubt that plants storing large amounts of chlorine and other toxic chemicals are potential terrorist targets.” These chemicals are even more vulnerable while in transit, as the Wall Street Journal proved by following graffiti artists as they “tagged” chlorine tank cars within site of the US Capitol building, long after 9-11.

The chemical industry’s own estimates reveal that if the chlorine from just one tank car were released by accident, sabotage or direct attack, the toxic gas could travel two miles in 10 minutes and remain lethal as far away as 20 miles.

Based on testimony by Dr. Jay Boris, Chief Scientist at the US Naval Research Laboratory, 3 minutes after a catastrophic rupture of a rail car in Washington, DC, a lethal cloud could reach the National Mall. On July 4th, when thousands gather to watch the fireworks display, people could die at the rate of 100 per second.

For this reason, Washington DC’s water treatment plant phased-out chlorine gas after 9-11. In New Jersey, after the passage of the Toxic Catastrophe Prevention law, the number of water works using chlorine has dropped from 575 in 1988 to just 22 in 2001.

These precautions are laudable, and verify chlorine reduction as a legitimate chemical security strategy. But ten times more chlorine is destined for PVC plastic than for municipal water treatment. PVC plastic can contain up to 50% chlorine by weight. By comparison, household bleach is typically less than three percent chlorine.[1]

Building materials account for more than 70% of all products manufactured of PVC. If we are willing to change the way we sanitize our drinking water in order to chip away at 5% of the vulnerable chlorine stockpile, what is the overriding interest that justifies keeping nearly ten times that amount on tap to make faux clapboard siding, picket fences, and vinyl flooring?

In an era of security alerts Yellow, Orange and Red, how can PVC be considered green?

SOURCES

  1. Calculation based on a 6% sodium hypochlorite solution, sodium hypochlorite is 50% chlorine.

Lessons From The Formosa PVC Plant, Illiopolis, Illinois

One morning ten years ago, I was at work on a book about environmental health when the phone rang. It was my Uncle Roy. He wanted me to know that a developer had come to town peddling a plan to construct a giant waste incinerator in the cornfield next to his own. What the man was planning to burn in it, he said, was old auto interiors, including a lot of PVC plastic. If the people of the township went along, the company would build the school a new library.

Now how did they know we needed a library, my uncle wondered. And what did I know about a chemical called dioxin? Funny he should ask. I was just drafting that chapter.

So I took leave of the Harvard Medical School Library and went back home to library-less central Illinois to throw my hat in the ring with my mother’s brother and a group of other farmers who had vowed to fight the incinerator.

And we won. Not only did Forrest, Illinois vote down the incinerator plan, it was defeated in six other small, impoverished farming communities where the same developer had dangled it. People looked out at their turkeys, hogs, and fields of corn and imagined what could happen if one semi-truck full of dioxin-laden incinerator ash overturned on a windy day. It just wasn’t worth the risk, they decided.

A decade later, central Illinoisians are confronted with a similar choice. This time it involves the manufacture of PVC rather than its destruction.

On April 23, 2004, the PVC plant in Illiopolis, Illinois exploded, spewing fireballs into the night sky, cutting power and water, and sending all of the village’s 900-something inhabitants into makeshift shelters in distant towns. Four workers were killed instantly. Three were hospitalized.

The U.S. Chemical Safety and Hazard Investigation Board conducted an investigation of the long-term environmental health effects of the explosion. Its chairwoman, Carolyn W. Merritt, called the explosion at Illiopolis among the most serious the agency has ever investigated. So far, no signs of air or water contamination have been uncovered. On the other hand, at this writing, investigators were not able to get closer than a quarter mile to the plant because of safety concerns.

But, let’s suppose that no chemical contamination from the plant’s destruction was found. Let’s imagine that thousands of pounds of vinyl chloride and vinyl acetate-which workers were mixing at the time of detonation-somehow all burned up without leaving behind any toxic residues in the community’s air or water or farm fields. It would still be a bad idea to rebuild this plant. Which is the current plan.

Each year, the Illiopolis PVC plant releases into the air more than 40,000 pounds of vinyl chloride, a recognized human carcinogen and reproductive toxicant. It releases another 40,000 pounds of vinyl acetate, a suspected carcinogen and neurotoxin. In other words, under normal operating conditions, this plant routinely discharges into the surrounding community more than 40 tons of toxic chemicals annually. That works out to 220 pounds of known and probable carcinogens every single day. The weight of a large man.

Such releases make this plant one of Illinois’ biggest polluters. But when you stack the Illiopolis facility next to all the other PVC plants in the United States, of which there are about 40, it pales in comparison. Its emissions are far from the worst. (Oxyvinyl in Pasadena, Texas releases more than 100,000 pounds of vinyl chloride annually.)

Even absent horrific accidents like the one in Illiopolis, which made headlines across the world, there seems to be no way of making PVC without contaminating somebody’s beloved hometown with cancer-causing substances. And that fact alone should be sufficient to compel us to seek out substitutes for PVC for all its various uses.

Here are the names of those who died in the Illiopolis explosion: Joseph Machalek, age 50; Larry Graves; age 47; Glenn Lyman, age 49; Linda Hancock, age 56.

What are the names of those who have died of cancer caused by the routine operation of this same plant over the years? Who have suffered miscarriages, birth defects, or neurological disorders due to their constant exposure to reproductive and neurological poisons? It is an unknown and unknowable number. But it may well exceed four. And it may be too high a price to pay for vinyl.

Sandra Steingraber, Ph.D., grew up in Pekin, Illinois. She is a biologist and author of the book Living Downstream: An Ecologist Looks at Cancer and the Environment. She is currently on the faculty of Ithaca College in New York.

In the last 40 years, polyvinyl chloride plastic (PVC) has become a major building material. Global vinyl production now totals over 30 million tons per year, the majority of which is directed to building applications, furnishings, and electronics.

The hazards posed by dioxins, phthalates, metals, vinyl chloride, and ethylene dichloride are largely unique to PVC, which is the only major building material and the only major plastic that contains chlorine or requires plasticizers or stabilizers. PVC building materials therefore represent a significant and unnecessary environmental health risk, and their phase-out in favor of safer alternatives should be a high priority. PVC is the antithesis of a green building material. Efforts to speed adoption of safer, viable substitute building materials can have significant, tangible benefits for human health and the environment.  This report describes the full life cycle of PVC in the contemporary building industry from production to disposal.