Some people can probably name a chemical that contributes to climate change, whether that is carbon dioxide or methane. But what about other chemicals that you are not as familiar with? In the building materials world, these may include fluorinated blowing agents used in some foam insulation. The agents either have high global warming potential (GWP) or use chemicals in their production that have high GWP.1 Another example is the release of the toxic, global warming, and ozone-depleting chemical carbon tetrachloride in the enormous supply chain of vinyl products, otherwise known as poly vinyl chloride (PVC).2 Purveyors of vinyl products, you may unwittingly be contributing to global warming! 

Yes, the way in which certain chemicals contribute to climate change is important, but this interplay is not the only consequence of chemicals on our climate. Climate change is also altering how toxic chemicals impact our health and the health of the environment – as the world warms, reducing our exposure to toxic chemicals becomes ever more important.

1. Temperatures affect how chemicals behave – warmer temperatures increase our exposure to toxic chemicals—.3 Higher temperatures can allow certain chemicals to vaporize more easily and enter the air we breathe.4 Warmer temperatures on Earth can also encourage the breakdown of some chemicals into toxic byproducts.5
2. Impacts of extreme weather events include concentrated releases of chemicals—catastrophic weather-related events such as hurricanes, fires, etc. can result in the release of toxic chemicals into the air when homes burn, or as factories in the Gulf region are damaged or destroyed.6 These events are becoming more and more frequent and will continue to expose people and the planet to highly concentrated chemical doses.
3. Climate change can exacerbate the health impacts of air pollution—volatile organic compounds released by chemical products contribute to the production of smog, leading to poor air quality which can negatively impact the lungs or exacerbate respiratory diseases such as asthma or Chronic Obstructive Lung Disease.7 Warmer temperatures amplify these impacts.8 As the largest source of air pollutants slowly transitions from transportation sources to chemical products, and as the earth warms, smart product choices will have even more impact on air quality.9
   
4. Toxic chemicals may hinder the body’s ability to adapt to climate change—in recent years, studies discovered that many toxic chemicals are endocrine disruptors.10 Animal studies have highlighted that endocrine-disrupting chemicals can alter metabolism and hinder animals’ ability to adapt to changing temperatures.11 While these findings were in animals, similar effects occur in humans as well, particularly in communities without access to heating or air conditioning.
5. Toxic chemicals increase communities’ vulnerability to climate change effects—toxic chemicals are an environmental justice issue. Ever heard of Cancer Alley? Cancer Alley is a predominantly African American community located in Southern Louisiana right next door to factories pumping out toxic chemicals every day.12 This 100 mile stretch of land is home to 25 percent of the nation’s petrochemical manufacturing and a large portion of its PVC supply chain.13 Aptly named, the cancer rate in this area is higher than the state and national cancer rate.14 Cancer Alley’s location right next to the Gulf Coast also increases its vulnerability to hurricanes and tropical storms. As climate change increases the frequency of extreme weather events, the impacts of toxic chemicals on this community also deepens.

While most toxic chemicals do not cause climate change, they do affect how climate change might impact you. These impacts compound as more chemicals are produced or utilized.15 In 1970, the U.S. produced 50 million tons of synthetic chemicals.16 In 1995, the number tripled to 150 million tons, and today, that number continues to increase.17

Very few of the tens of thousands of chemicals on the marketplace are fully tested for health hazards, and details on human exposure to these chemicals are limited.18 We are exposed to these chemicals every day, in varying quantities and mixtures. Over a lifetime, the small exposures add up. Predictions of health outcomes from long-term exposure are already fuzzy at best, but add on the component of climate change and the mystery deepens.19 While researchers continue to study climate change and chemicals to answer the questions we have, there are steps that we can take to help mitigate the negative impact of climate change on chemicals.

Habitable’s Small Piece of the Pie — How We’re Keeping Consumers Safe 

We cannot remove all chemicals from our lives and many play important roles, but, we can follow the precautionary principle. If there is a less toxic chemical or product available that meets our requirements, we should use it. At Habitable, our work is guided by the precautionary principle—otherwise known as ‘better to be safe than sorry.’ Our chemical and product guidance provides advice on better products.Empowering industry to choose safer chemicals and products helps reduce the burden of toxic chemicals on all people and the planet – especially our most vulnerable populations.

Why We Can and Must Do Better  

Between climate change and toxic chemicals, it could be easy to push toxic chemicals to the side as a someday problem and choose to tackle climate change first. But the truth is that the impacts of toxic chemicals are real and happening today and will only get worse in a warming world. These two issues are connected and influence each other’s outcomes. Climate change is having a significant impact on our world, but prioritizing reduction of  toxic chemicals can reduce the negative consequences that climate change will have on chemicals, and consequently on us.

While this photo considers height as an inequity, in real life, income, access to food and health care are often at the heart of equity discussions. Surprisingly, a critical topic often overlooked in the equity discussion is where we spent 90 percent of our lives—in buildings.1 

Oregon Metro, otherwise known simply as Metro, released a report discussing toxics reduction and equity. Its section on building materials connects building materials and equity, calling attention to the need to reduce community exposure to toxic building materials in an equitable manner. Building materials seem harmless and inert in our homes, offices, schools, or cafes. But in 1991, the Environmental Protection Agency (EPA) characterized indoor air pollution as “one of the greatest threats to public health of all environmental problems”.2 

A large proportion of indoor air pollution stems from building materials.3 In particular, asthmagens are of highest concern and contribute to indoor air pollution through the release of chemicals from the surface of building finishes.4 For example, carpet, furniture and wall decor release chemicals through degradation or abrasion.5 The chemicals end up in dust in our homes and can enter our bodies through the lungs, skin or mouth.6 Volatile organic compounds emitted from paints are also of concern.7 In fact, a study of children in Australia showed a strong association among indoor home exposure to VOCs and increased risk of asthma.8 Over 70 percent of building material asthmagens identified by Healthy Building Network (HBN) researchers  are not covered by leading indoor air quality testing standards.9  These hazardous wastes and products used in building materials disproportionately affect historically marginalized communities of color, children and low-income families.10 

Equity in housing is especially important for many families with low incomes who live in multifamily housing.11  Multifamily housing often poses challenges to achieving better air quality as pollutants easily travel between units due to inadequate ventilation. Residents are usually unable to improve building infrastructure themselves.12  

Incorporating building materials into the equity discussion is only part of the solution. Product testing for chemicals of concern, biomonitoring, community health impact research, chemicals research, advocacy and education all stand to make a larger collective impact.13 

For funders looking to increase diversity and equity initiatives in their grant making, the building industry provides a blooming landscape to foster substantial impact within communities. Here are some key questions to consider when funding proposals:

• What is the specific toxics reduction action?
• Are there particular populations or communities impacted more than the general population by the chemical/product/system in question?
• Does the action consider and address the structural barriers and existing resources available to a population? 
• Does the recommendation ameliorate the disparity or gap in accessing resources for a marginalized community? 

So often, sustainability standards and initiatives are cost prohibitive, developed for those with the most access and resources, in hopes that “someday” the solutions will trickle-down. In the meantime, children and the populations with the lowest income continue to bear the burden of toxic exposures and preventable health consequences. Habitable’s Informed™ healthy product guidance is changing that old, unsuccessful paradigm. Our resources will result in healthier products for everyone, and amplify the prospect for a healthier planet. 

Every day we come in contact with a large number of chemical products. Think of the last time you walked through a space being remodeled, or sat in a new car and thought “what’s that smell?” Your body notices that smell because a chemical or substance is interacting with the smell receptors in your nose. The same characteristics that allow it to interact with your nose could make those chemicals affect the body in other ways too—sometimes causing harm. The more invisible moments occur when sleeping on your mattress filled with flame retardants or using your personal care products while getting ready for work. Perhaps you work in a factory, as a contractor installing products, or some other job requiring direct contact with a variety of chemicals. The list (both visible and invisible) goes on and on. While a one-time exposure might not lead to health effects, a life-time of exposure and buildup to these chemicals can. More and more scientific evidence links these chemical exposures to diseases like cancer and diabetes, as well as developmental delays, reproductive health issues, and Autism Spectrum Disorder1. 

There are three main exposure pathways: 1) inhalation – breathing in contaminated air, 2) ingestion – the inadvertent passing of dust or other chemical residues from hands to mouth, and 3) because our skin is like a sponge – absorption through dermal contact. According to the Environmental Working Group (EWG), babies still in the womb are exposed to more than 200 chemicals that pass from their mother through the umbilical cord2. This should make you wonder—what are the chemicals I may not realize are entering my body? There is a term used to describe the load of chemicals in the human body—body burden.

You can also download their Detox Me Now App for more tips.

Biomonitoring studies similar to Silent Spring’s are springing up in recent years, as have articles about their results, such as this story in the Guardian. For only a few hundred dollars, consumers can know the exact chemical composition of their bodies. For those who find sample submission undesirable, HBN has added a new feature in our Pharos platform that provides links to biomonitoring databases with information on chemicals identified in the bodies of individuals from different regional communities. The results continually shed light on the need for greater industrial transparency and a transition to safer products. 

This is one more example of why HBN passionately paves the way to safer products, offering recommended alternatives from expert chemical analysis and by fostering collaborative industry partnerships.

At this point, there is an urgency because people are now experiencing the effects of a warming planet:storms, fires, rising tides, health impacts from warmer temperatures, and more.

To date, climate plans have focused on strategies related to renewable and clean energy, greater efficiency, emissions reduction, etc., especially as it relates to building operations and transportation. However, that is only one side of the (enormous) coin, and it misses key opportunities on the opposite side. It is akin to making the decision to improve your health by incorporating an exercise plan, but continuing a diet of nutritionally deficient and unhealthy foods. You will only get so far, and your dedication to exercise will be undercut by your fast food burgers and supersized fries. 

The other side of the coin? If building and transportation energy and emissions reduction is “heads,” what could be so immense that it fills the flipside? The “tails” of that coin is the vast quantities of products being produced, its emissions and pollution, and the need for toxic chemical mitigation. The missing piece in effective climate mitigation and improved global health is a toxic-free, recyclable product cycle (low-waste and closed-loop).

As energy efficiency and renewable energy gains reduce the carbon footprint of the transportation and building operations sectors, addressing product production assumes an even greater importance. Successfully addressing climate change requires a revolutionary change in how we design and manufacture materials, towards a circular, closed-loop economy. But materials cannot flow effectively in a closed-loop if they are contaminated with toxic chemicals. Safe first, and then circular is possible. 

The urgency to mitigate toxics must be on par with the urgency for clean and renewable energy – they are two sides of the same coin. Failing to recognize this, and create holistic, compatible solutions, will undermine our goals to manage climate change and improve global health. 

The announcement came after lengthy negotiations led by the Mind The Store Campaign, a grassroots effort supported by the Healthy Building Network’s (HBN) cutting-edge research on building products.  Mind The Store is challenging the country’s largest retailers to restrict 100 hazardous chemicals in the products they sell. Also today, the Mind The Store campaign released a report identifying phthalates and other chemical hazards detected in vinyl flooring products.

Perfluorinated compounds (PFCs) are manmade compounds, based on the element fluorine, and are the key ingredients in stain- and water-repellent treatments such as Teflon®, Crypton® and Crypton Green®, Gore™, and Stainmaster®, and in nanotech products such as Nano-Tex™ and GreenShield™.[2] Scientists have raised concerns about PFCs because they are persistent, bioaccumulative, and toxic. Moreover, biomonitoring studies confirm widespread human exposure to this class of compounds.

Scientific studies have linked PFCs with developmental toxicity, cancer, thyroid, liver and immune system functions, cholesterol increases, and low birth measurements in newborn humans.[3] The health issues associated with PFCs, coupled with alarming data about the increasing chemical burden of these compounds in our bodies,[4] as well as the widespread exposure in wildlife, have prompted scientists and public health experts to express increasing concern about continued use of these chemicals.

In May 2009, the Stockholm Convention on Persistent Organic Pollutants (POPs) added PFOS to a growing list of chemicals recognized by international treaty as chemicals of greatest concern to be reduced or eliminated in the global environment, putting them in league with widely recognized threats such as dioxin and PCBs.

In the U.S., most major fabric treatment brands continue to use PFCs as chemical manufacturers rush to replace the most well-studied PFCs with similar fluorinated compounds that have not been heavily scrutinized. Although chemical manufacturers such as DuPont resist releasing information about the new compounds, it is clear that some are virtually unstudied, and some that scientists have studied are breaking down to PFOS and perfluorooctanic acid (PFOA), which would add to the reservoir of these persistent contaminants in the general environment. In June 2008, the Environmental Working Group (EWG) released a report on PFCs, which uncovered evidence that manufacturers’ own tests showed that many of the alternative chemicals lead “to a conclusion of substantial risk to human health or to the environment.”[5]

Like nuclear waste, the problem of PFCs isn’t going away. Still, there are steps that can be taken today to stem the tide of PFCs accumulating in our bodies. For many of the PFC applications, we can start out by simply asking ourselves whether we really need these chemicals at all.

For those wanting to understand more about PFCs and potential health concerns, HBN and Kaiser Permanente have produced a paper that examines PFCs in more detail.

Everyone has heard the news about the health concerns associated with bisphenol A (BPA) leaching from baby bottles, food can liners and perhaps most famously those distinctive polycarbonate plastic water bottles popularized by Nalgene.[1] Last May, Chicago became the first city in the U.S. to ban the sale of baby bottles and sippy cups made from BPA. Few, however, are aware that BPA is a chemical component of epoxy resins used in a wide range of building materials, typically paints, sealants, adhesives and fillers,[2] that may put manufacturing workers, installers, and building occupants at risk.

Epoxy resins are used in building materials, often listed on a material safety data sheet as a proprietary mixture, without disclosure that the resin is made from BPA. While manufacturers claim that the BPA in epoxy resins is consumed entirely in the production process and does not show up in the final products, scientists investigating the metabolic breakdown of epoxy resins during occupational exposure have found that epoxy resin products can be metabolized in the human body back into BPA and may impact the endocrine and reproductive system of those exposed.[3]Animal studies have linked this hormone-disrupting chemical to prostate cancer, breast cancer, pre-diabetes (insulin resistance), abnormal fat metabolism, early puberty, and changes in the way the brain develops resulting in behavioral abnormalities.[4] 

The BPA expert panel from the Center for Evaluation of Human Risks to Reproduction raised concern about BPA in epoxy-based resins, reporting to the National Toxicology Program that, “several studies collectively suggest hormonal effects of bisphenol A exposure, including one in occupationally exposed male workers likely exposed through multiple routes including inhalation…”[5] The NTP’s final monograph states that “a number of studies, when considered together, suggest a possible effect on reproductive hormones, especially in men exposed to higher levels of bisphenol A in the workplace.”[6] Germany has already instituted occupational exposure limits for bisphenol A.[7]

It is likely that BPA in building products will become subject to greater health and safety regulation, but responsible specifiers do not need to wait for the regulatory system to catch up with the science to protect their clients. Products are available that can replace epoxy-based coatings and adhesives. For example, many paint companies now offer high-performance low-VOC water-based acrylic paints and acrylic-based adhesives for flooring, carpets, and wall covering. For applications where high-performance BPA-free substitutes are not yet available, the act of asking manufacturer reps for products without bisphenol A is an important step to prod the industry to bring safer high performance alternatives to market.

For a comprehensive discussion of the emerging science on BPA risks, read “Bisphenol A in Building Materials: High Performance Paint Coatings.”

Aaron Freiwald is an attorney representing the cancer victims in a class action lawsuit against Rohm & Haas, which bought the suspect facility from the Morton Chemical Company in 1999. According to Freiwald, “By the time we are done with this case, the association between vinyl chloride and brain cancer is going to be much stronger. They are going to have to revise the way current textbooks discuss cancer risks associated with vinyl chloride.”

One critical factor in the case is the clear connection between the vinyl chloride and the cancers.  It can be difficult to prove a specific chemical causes a specific cancer because so often people have multiple exposures to carcinogens.  But, Lake McCollum is an isolated community.  There are no other significant industrial sources of chemical contamination to which the 14 victims have been exposed.  According to the International Agency for Research on Cancer (IARC), vinyl chloride is carcinogenic to humans and has been associated with brain cancer.

Phthalates are used as plasticizers to soften polyvinyl chloride plastic, also known as PVC or vinyl, including a wide range of building products such as vinyl flooring, wallcovering and upholstery.

Phthalate plasticizers are not chemically bound to PVC. They have been found to leach, migrate or evaporate into indoor air and atmosphere, foodstuff, IV solutions and other materials, etc. Consumer products containing phthalates can result in human exposure through direct contact and use, indirectly through leaching into other products, or general environmental contamination. Humans are exposed through ingestion, inhalation, and dermal exposure during their whole lifetime, starting in the womb. Phthalates come in many different formulas. Most haven’t been tested or examined at all for human health impacts. The Consumer Product Safety Commission has noted that one phthalate formula common to certain building materials — DINP [1] — is a mixture of up to 100 chemical variants, of which only five have been minimally studied [2]. Others have been found to pose a risk of serious negative health impacts at very low doses.

Phthalates have been shown to have negative effects on human health including interference with the natural functioning of the hormone system, and reproductive and genital defects. Phthalates may lower sperm count and are associated with the risk factors for testicular cancer, as well as early onset of puberty and premature birth.

In June 2005, HBN discussed recent research findings that the cumulative impact of different phthalates leads to an exponential increase in associated harm, and documented levels of phthalates found in humans at levels higher than levels shown to cause adverse health effects. A 2007 study concluded that the exposure of children to phthalates exceeds that in adults, warning, “Current human biomonitoring data prove that the tolerable intake of children is exceeded to a considerable degree, in some instances up to 20-fold” [3].

Phthalates have been found in high quantities in studies of household dust. Other studies have documented links between childhood asthma and phthalate exposure from vinyl flooring. Because phthalates are not a volatile organic compound (VOC), however, they are usually not accounted for by indoor air quality standards such as those used to certify green building materials.

The CSB Investigation Report is made all the more relevant to green building professionals in light of the USGBC’s finding that PVC flooring ranked absolute worst in both human health and environmental factors compared to the alternatives reviewed. The destroyed factory, owned by Formosa Plastics, had been a major supplier of vinyl resin for Armstrong floors.

The CSB is the industrial equivalent of the National Transportation Safety Board (NTSB), the agency that rushes investigators to the scene of plane crashes, train derailments and the like. [1] The CSB’s March 6, 2007 report found among other things that the cause of this accident, “inadvertently draining a reactor, is a serious hazard in the PVC manufacturing process.” [2] Indeed just 60 days before the fatal explosion, workers at the same facility accidentally released an undisclosed amount of vinyl chloride. The report also notes that 8,000 pounds of vinyl chloride were released by accident in June 2003 at the company’s Baton Rouge, LA facility. [3] A year after the explosion, in May 2005, another 2,500 pounds of vinyl chloride were accidentally released from the company’s Delaware City, DE location. [4] Each release was caused by the same problems which led to the catastrophe at the Illiopolis facility in April 2004. Other PVC factories owned by Formosa have also suffered catastrophic explosions in the recent past. [5]